Coordination-assisted, transition-metal-catalyzed enantioselective desymmetric C-H functionalization

被引：37
|
作者：
Yu, Xin [1 ]
Zhang, Zhuo-Zhuo [2 ]
Niu, Jun-Long [3 ]
Shi, Bing-Feng [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[2] Chengdu Univ, Sch Food & Biol Engn, Chengdu 610106, Sichuan, Peoples R China
[3] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450001, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 05期
基金：
中国博士后科学基金;
关键词：
PLANAR CHIRAL FERROCENES; C(SP(3))-H BONDS; ASYMMETRIC-SYNTHESIS; ALIPHATIC AMIDES; NATURAL-PRODUCTS; ACTIVATION; ARYLATION; LIGANDS; BORYLATION; ALKYLATION;
D O I：
10.1039/d1qo01884a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition-metal-catalyzed asymmetric C-H functionalization has gradually emerged as a powerful tool for the creation of structural and chiral complexity in an atom- and step-economical fashion. The nature of this strategy provides a variety of methodologies to overcome the limitation of enantioselective desymmetrization caused by the synthesis of preformed multifunctional symmetric substrates. This review aims to summarise recent advances in transition-metal-catalyzed enantioselective desymmetric C-H functionalization reactions via coordination-assisted metal insertion, covering the literature from 2008 to June 2021. The mechanistic pathway and the modes of stereocontrol are discussed where appropriate.
引用
收藏
页码：1458 / 1484
页数：27
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