Crystal and molecular structures of 2,4-diacetyl-5-hydroxy-5-methyl-3-phenyl-N-benzyl-1-cyclohexenylamine

被引：1

作者：

Sorokin, V. V. ^{[1
]}

Grigor'eva, E. A. ^{[1
]}

Poplevina, N. V. ^{[1
]}

Kriven'ko, A. P. ^{[1
]}

Solodovnikov, S. F. ^{[2
]}

机构：

[1] NG Chernyshevskii Saratov State Univ, Saratov, Russia

[2] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 05期

关键词：

single crystal X-ray diffraction; enamines; cyclohexenes;

D O I：

10.1007/s10947-007-0146-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,4-Diacetyl-5-hydroxy-5-methyl-3-phenyl-N-benzyl-1-cyclohexenylamine is obtained by benzylamination of 2,4-diacetyl-5-hydroxy-5-methyl-3-phenylcyclohexanone. Based on spectral and X-ray structural data, the half-chair conformation of the cyclohexenyl ring and the pseudoequatorial orientation of all substituents, except for the pseudoaxial OH-group, are established. An intramolecular hydrogen bond N-H center dot center dot center dot O=C is revealed.

引用

页码：981 / 985

页数：5

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