Octabutyl-1κ2C,2κ2C,3κ2C,4κ2C-bis-μ3-oxo-1:2:3κ3O;1:3:4κ3O-tetrakis-[μ-(2-pyridinecarboxylato N-oxide)]-1κ2O,O′:2κO;2κO:3κ2O,O′;3κ2O,O′:4κO;1κ2O,O′:4κO-tetratin hydrate

被引：10
|
作者：
Ng, SW [1 ]
机构：
[1] Univ Malaya, Inst Postgrad Studies & Res, Kuala Lumpur 50603, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S010827019701891X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The unit cell of the title compound, bis[1,1,3,3-tetrabutyl-1,3-bis(picolinato N-oxide)distannoxane] hydrate, [Sn-4(O)(2)(C4H9)(8) (C6H4NO3)(4)]. H2O, contains two independent centrosymmetric dicarboxylatotetraorganodistannoxane dimers, one of which is hydrogen bonded to two water molecules. Both dimers possess a planar Sn2O2 core unit, the O atoms of which are covalently bonded to two [dibutyl(picolinato N-oxide)tin] units. The endocyclic Sn atoms (of the Sn2O2 core units) are six-coordinate in C2SnO4 skew-trapezoidal bipyramidal environments whereas the exocyclic Sn atoms (of the [dibutyl(picolinalo N-oxide)tin] units) are seven-coordinate in trans-C2SnO5 pentagonal bipyramidal environments.
引用
收藏
页码：752 / 755
页数：4
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