Yttrium(III) and lanthanum(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and study by mass spectrometry, X-ray diffraction analysis, and 89Y and 139La NMR spectroscopy

被引：1

作者：

Taidakov, I. V. ^{[1
]}

Strelenko, Yu. A. ^{[2
]}

Borisov, R. S. ^{[3
]}

Temerdashev, A. Z. ^{[4
]}

Datskevich, N. P. ^{[1
]}

Vitukhnovskii, A. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Lebedev Phys Inst, Moscow 119991, Russia

[2] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow 119991, Russia

[3] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119992, Russia

[4] Kuban State Univ, Krasnodar 350640, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 41卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

COMPLEXES;

D O I：

10.1134/S1070328415040089

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of LaCl3 and YCl3 with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dione (HL) and 1,10-phenanthroline (Phen) in the presence of a base afford complexes [La(L)(3)(Phen)] (I) and [Y(L)(3)(Phen)] (II). Unstable solvates I center dot iso-PrOH (III) and II center dot iso-PrOH (IV) are obtained from solutions of the complexes in 2-propanol, and their structures are determined by X-ray diffraction analysis (CIF files CCDC 1026802 (III) and 1026808 (IV)). The compositions of the complexes are additionally studied by H-1, C-13, Y-89, and La-139 NMR methods. Fragmentation is studied by laser desorption/ionization (LDI) and electrospray ionization (ESI) mass spectrometry.

引用

页码：230 / 239

页数：10

共 19 条

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