Yttrium(III) and lanthanum(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and study by mass spectrometry, X-ray diffraction analysis, and 89Y and 139La NMR spectroscopy

被引：1

作者：

Taidakov, I. V. ^{[1
]}

Strelenko, Yu. A. ^{[2
]}

Borisov, R. S. ^{[3
]}

Temerdashev, A. Z. ^{[4
]}

Datskevich, N. P. ^{[1
]}

Vitukhnovskii, A. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Lebedev Phys Inst, Moscow 119991, Russia

[2] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow 119991, Russia

[3] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119992, Russia

[4] Kuban State Univ, Krasnodar 350640, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 41卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

COMPLEXES;

D O I：

10.1134/S1070328415040089

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of LaCl3 and YCl3 with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dione (HL) and 1,10-phenanthroline (Phen) in the presence of a base afford complexes [La(L)(3)(Phen)] (I) and [Y(L)(3)(Phen)] (II). Unstable solvates I center dot iso-PrOH (III) and II center dot iso-PrOH (IV) are obtained from solutions of the complexes in 2-propanol, and their structures are determined by X-ray diffraction analysis (CIF files CCDC 1026802 (III) and 1026808 (IV)). The compositions of the complexes are additionally studied by H-1, C-13, Y-89, and La-139 NMR methods. Fragmentation is studied by laser desorption/ionization (LDI) and electrospray ionization (ESI) mass spectrometry.

引用

页码：230 / 239

页数：10

共 19 条

[1] Yttrium(III) and lanthanum(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and study by mass spectrometry, X-ray diffraction analysis, and 89Y and 139La NMR spectroscopy
I. V. Taidakov
Yu. A. Strelenko
R. S. Borisov
A. Z. Temerdashev
N. P. Datskevich
A. G. Vitukhnovskii
Russian Journal of Coordination Chemistry, 2015, 41 : 230 - 239
[2] Neodymium(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and photophysical properties
I. V. Taidakov
A. N. Lobanov
L. S. Lepnev
A. G. Vitukhnovskii
Russian Journal of Coordination Chemistry, 2014, 40 : 16 - 22
[3] Neodymium(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and photophysical properties
Taidakov, I. V.
Lobanov, A. N.
Lepnev, L. S.
Vitukhnovskii, A. G.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (01) : 16 - 22
[4] Synthesis and crystal structure of the Tb(III) complex with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione and 1,10-phenanthroline
Taidakov, I. V.
Zaitsev, B. E.
Lobanov, A. N.
Vitukhnovskii, A. G.
Starikova, Z. A.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (04) : 300 - 304
[5] Synthesis and crystal structure of the Tb(III) complex with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione and 1,10-phenanthroline
I. V. Taidakov
B. E. Zaitsev
A. N. Lobanov
A. G. Vitukhnovskii
Z. A. Starikova
Russian Journal of Coordination Chemistry, 2012, 38 : 300 - 304
[6] Synthesis and Luminescence Properties of Neutral Tm(III), Dy(III), and Gd(III) Complexes with 1,3-Bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione and 1,10-Phenanthroline
Taidakov, I. V.
Zaitsev, B. E.
Lobanov, A. N.
Vitukhnovskii, A. G.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (06) : 870 - 873
[7] Synthesis and luminescence properties of neutral Tm(III), Dy(III), and Gd(III) complexes with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedione and 1,10-phenanthroline
I. V. Taidakov
B. E. Zaitsev
A. N. Lobanov
A. G. Vitukhnovskii
Russian Journal of Inorganic Chemistry, 2012, 57 : 870 - 873
[8] Tris(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dionato)(dimethanol)terbium(III): synthesis, crystal structure, and luminescent properties
I. V. Taydakov
R. I. Avetisov
N. P. Datskevich
Russian Journal of Coordination Chemistry, 2019, 45 : 883 - 888
[9] The complex Eu(phen)L3•5CH2Cl2 (HL is 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dione): synthesis, crystal structure, and luminescent properties
Taydakov, I. V.
Zaitsev, B. E.
Krasnosel'skiy, S. S.
Starikova, Z. A.
Borisov, R. S.
RUSSIAN CHEMICAL BULLETIN, 2011, 60 (08) : 1595 - 1600
[10] Tris(1,5-Dimethyl-1H-Pyrazol-4-Yl)-4,4,4-Trifluorobutane-1,3-Dionato)(dimethanol)terbium(III): Synthesis, Crystal Structure, and Luminescent Properties
Taydakov, I. V.
Avetisov, R. I.
Datskevich, N. P.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (12) : 883 - 888

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