Hydroformylation of internal olefins to linear aldehydes with novel rhodium catalysts

被引：1
|
作者：
van der Veen, LA [1 ]
Kamer, PCJ [1 ]
van Leeuwen, PWNM [1 ]
机构：
[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 03期
关键词：
homogeneous catalysis; hydroformylations; phosphorus heterocycles; rhodium;
D O I：
10.1002/(SICI)1521-3773(19990201)38:3<336::AID-ANIE336>3.0.CO;2-P
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.
引用
收藏
页码：336 / 338
页数：3
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