Hydroformylation of internal olefins to linear aldehydes with novel rhodium catalysts

被引：1

作者：

van der Veen, LA ^{[1
]}

Kamer, PCJ ^{[1
]}

van Leeuwen, PWNM ^{[1
]}

机构：

[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 03期

关键词：

homogeneous catalysis; hydroformylations; phosphorus heterocycles; rhodium;

D O I：

10.1002/(SICI)1521-3773(19990201)38:3<336::AID-ANIE336>3.0.CO;2-P

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119°, respectively, are suited for this.

引用

页码：336 / 338

页数：3

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