Oxidative transformations of amidophenolate complexes of gallium(III)

被引：11

作者：

Piskunov, A. V. ^{[1
]}

Ershova, I. V. ^{[1
]}

Fukin, G. K. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2014年 / 63卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

redox-active ligand; o-iminosemiquinolate; gallium; X-ray diffraction; EPR; METALS;

D O I：

10.1007/s11172-014-0528-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of the earlier synthesized [4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato]methylgallium(III) (1a) and [4,6-di-tert-butyl-N- (2,6-diisopropylphenyl)-o-amidophenolato]iodogallium(III) (1b) by different reagents, such as mercury(II) salts, molecular iodine, and tetramethylthiuram disulfide, was studied. The oxidation of the starting diamagnetic compounds gives pentacoordinated gallium(III) bis-o-iminosemiquinolates 4-7 as the major products, which are generated as a result of the further disproportionation of intermediate monoradical tetracoordinated metal complexes.

引用

页码：916 / 922

页数：7

共 50 条

[21] Synthesis and characterization of dialkyldithiophosphate complexes of gallium(III)
Pahari, D
Jain, VK
MAIN GROUP METAL CHEMISTRY, 1997, 20 (11): : 691 - 696
[22] SYNTHESIS OF GALLIUM(III) COMPLEXES WITH POLYDENTAL ACIDOLIGANDS
ZHARKOV, AP
KULBA, FY
TITOVA, NA
KHAK, NK
ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (02): : 358 - 363
[23] Aluminum(III), gallium(III), and indium(III) 4-hydroxyacridinato complexes
Aiello, Iolinda
Aiello, Daniela
Ghedini, Mauro
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (20) : 3351 - 3365
[24] Tripodal iminophenolate ligand complexes of gallium(III), indium(III), and thallium(III)
Figuet, M
Averbuch-Pouchot, MT
d'Hardemare, AD
Jarjayes, O
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (08) : 2089 - 2096
[25] Complexes of a crown ether with gallium(III) iodide and indium(III) iodide
Kloo, LA
Taylor, MJ
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (15): : 2693 - 2696
[26] Spectroscopic studies of aqueous gallium(III) and aluminum(III) citrate complexes
Clausén, M
Öhman, LO
Persson, P
JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (03) : 716 - 726
[27] Synthesis and characterization of phosphinic and phosphate complexes of gallium(III) and indium(III)
Dutta, DP
Jain, VK
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2000, 166 : 15 - 26
[28] FLUORINE COMPLEXES OF ALUMINUM(III) AND GALLIUM(III) WITH ETHYLENEDIAMINE AND ITS DERIVATIVES
PETROSYANTS, SP
BUSLAEVA, ER
ZHURNAL NEORGANICHESKOI KHIMII, 1989, 34 (07): : 1648 - 1655
[29] Synthesis and Structural Studies of Gallium(III) and Iron(III) Hemicryptophane Complexes
Gosse, Isabelle
Robeyns, Koen
Bougault, Catherine
Martinez, Alexandre
Tinant, Bernard
Dutasta, Jean-Pierre
INORGANIC CHEMISTRY, 2016, 55 (03) : 1011 - 1013
[30] Stable Indium(III) and Gallium(III) Complexes as Candidates for Conjugation to Antibodies
J Labelled Compd Radiopharm, (421):

← 1 2 3 4 5 →