Titanium(IV) complexes of trianionic amine triphenolate ligands

被引：92
|
作者：
Kol, M [1 ]
Shamis, M
Goldberg, I
Goldschmidt, Z
Alfi, S
Hayut-Salant, E
机构：
[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel
[2] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[3] Coll Judea & Samaria, IL-44837 Ariel, Israel
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 04期
基金：
以色列科学基金会;
关键词：
phenolate ligands; tripodal ligands; titanium complexes; X-ray structure;
D O I：
10.1016/S1387-7003(01)00157-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two trianionic amine triphenolate ligands are introduced and their isopropoxide Ti(IV) complexes synthesized. The two complexes are mononuclear and C-3-symmetrical on the NMR timescale. High barriers to inversion (DeltaG double dagger > 65 KJ mol(-1)) between the enantiomers of each complex were found. The complex derived from the bulkier tripodal ligand shows a better resistance to hydrolysis. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：177 / 179
页数：3
相关论文
共 50 条
  • [41] Titanium complexes of amidophosphinimide ligands
    Alhomaidan, Osamah
    Beddie, Chad
    Bai, Guangcai
    Stephan, Douglas W.
    DALTON TRANSACTIONS, 2009, (11) : 1991 - 1998
  • [42] SYNTHESES AND CHARACTERIZATION OF BINUCLEAR MANGANESE(III,IV) AND MANGANESE(IV,IV) COMPLEXES WITH LIGANDS RELATED TO TRIS(2-PYRIDYLMETHYL)AMINE
    OKI, AR
    GLERUP, J
    HODGSON, DJ
    INORGANIC CHEMISTRY, 1990, 29 (13) : 2435 - 2441
  • [43] Titanium(IV) terminal hydroxo complexes containing chelating bis(phosphine oxide) ligands
    Yi, XY
    Williams, ID
    Leung, WH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (06) : 1315 - 1319
  • [44] Preparation of amino acid-bridged dicatechol ligands for dinuclear titanium(IV) complexes
    Albrecht, M
    Nolting, R
    Weis, P
    SYNTHESIS-STUTTGART, 2005, (07): : 1125 - 1135
  • [45] Syntheses of tridentate and tetradentate oxo-ligands used in octahedral titanium (IV) complexes
    Brechtelsbauer, Luke D.
    Fraser, Dayne D.
    Shaughnessy, Kevin H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [46] SYNTHESIS AND CHARACTERIZATION OF TITANIUM (IV) SCHIFF-BASE COMPLEXES .3. OCTAHEDRAL TITANIUM (IV) COMPLEXES OF SOME DIBASIC TERDENTATE SCHIFF-BASE LIGANDS
    ALYEA, EC
    MALEK, A
    MERRELL, PH
    TRANSITION METAL CHEMISTRY, 1979, 4 (03) : 172 - 178
  • [47] COMPLEXES OF METAL IONS WITH LIGANDS CONTAINING PHOSPHORUS OR ARSENIC .10. COMPLEXES OF ORTHO CARBMETHOXYPHENYLTERTIARYARSINES WITH TIN(IV) AND TITANIUM(IV) HALIDES
    SANDHU, SS
    SINGH, H
    INDIAN JOURNAL OF CHEMISTRY, 1971, 9 (03): : 267 - &
  • [48] Cyclometallaphosphazene complexes of titanium(IV)
    Paul, Yash
    Magotra, Suresh
    Pandey, Sushil K.
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2007, 37 (09) : 705 - 711
  • [49] Titanium (IV) starch complexes
    Tyrlik, SK
    Tomasik, P
    Anderegg, JW
    Baczkowicz, M
    CARBOHYDRATE POLYMERS, 1997, 34 (1-2) : 1 - 7
  • [50] C3 vanadium(V) amine triphenolate complexes:: Vanadium haloperoxidase structural and functional models
    Mba, Miriam
    Pontini, Marta
    Lovat, Silvia
    Zonta, Cristiano
    Bernardinelli, Gerald
    Kuendig, Peter E.
    Licini, Giulia
    INORGANIC CHEMISTRY, 2008, 47 (19) : 8616 - 8618
12345