Synthesis of the 1-hydroxy-closo-decaborate anion [1-B10H9OH]2-

被引：21
|
作者：
Bragin, VI
Sivaev, IB
Bregadze, VI
Votinova, NA
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] MV Lomonosov Fine Chem Technol Inst, Moscow 117571, Russia
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 11期
关键词：
closo-decaborate; derivatization; hydroxy derivative; diazonium derivative;
D O I：
10.1016/j.jorganchem.2005.01.053
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of the diazonium derivative of closo-decaborate anion with oxygen nucleophiles were studied. The reaction of [1-B10H9N2](-) with hydroxide ion gives the corresponding hydroxy derivative [1-B10H9OH](2-) in high yield. The reactions with OR (R = Me, Et, i-Pr, Ph) result in mixture of [I-B10H9OR](2)- and [a(2) -B20H18](4-). (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：2847 / 2849
页数：3
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