Platinum(II) and platinum(I) dinuclear hydrides: A fast-atom bombardment mass spectrometric study

被引:0
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作者
Banditelli, G
Bandini, AL
Minghetti, G
Seraglia, R
Traldi, P
机构
[1] CNR,CTR STUDIO STABIL & REATTIVITA COMPOSTI COORDINAZ,I-35100 PADUA,ITALY
[2] UNIV MILAN,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,CTR CNR,I-20133 MILAN,ITALY
[3] UNIV SASSARI,DIPARTIMENTO CHIM,I-07100 SASSARI,ITALY
[4] CNR,AREA RIC,I-35020 PADUA,ITALY
关键词
D O I
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中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The fast-atom bombardment (FAB) mass spectrometric behaviour of some platinum (II) and platinum (I) dinuclear hydrides has been studied by means of metastable ion studies, For all the examined compounds, the loss of the moieties bridging the two platinum centres is always observed, leading to structurally different product ions, Especially in tbe case of platinum (II) dinuclear hydrides, FAB mass spectra particularly rich in species in the range m/z 300-700 are obtained, generated by decomposition and rearrangement reactions.
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页码:1107 / 1112
页数:6
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