Two-electron aromatics containing three and four adjacent boron atoms

被引:17
|
作者
Präsang, C
Mlodzianowska, A
Geiseler, G
Massa, W
Hofmann, M
Berndt, A [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1351/pac200375091175
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A two-electron aromatic bis(tris-trimethylsilylmethylene)-substituted tetraborane(4) was found to be a useful precursor for the synthesis of two-electron aromatic tetraboranes(6), triboracyclopropanates, as well as tetraboranes(6) distorted toward triboracyclopropanates with boryl bridges. Bishomo two-electron aromatics with a borata bridge and a protonated borata bridge, respectively, are also presented.
引用
收藏
页码:1175 / 1182
页数:8
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