Two-electron aromatics containing three and four adjacent boron atoms

被引：17
|
作者：
Präsang, C
Mlodzianowska, A
Geiseler, G
Massa, W
Hofmann, M
Berndt, A [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
PURE AND APPLIED CHEMISTRY | 2003年 / 75卷 / 09期
关键词：
D O I：
10.1351/pac200375091175
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A two-electron aromatic bis(tris-trimethylsilylmethylene)-substituted tetraborane(4) was found to be a useful precursor for the synthesis of two-electron aromatic tetraboranes(6), triboracyclopropanates, as well as tetraboranes(6) distorted toward triboracyclopropanates with boryl bridges. Bishomo two-electron aromatics with a borata bridge and a protonated borata bridge, respectively, are also presented.
引用
收藏
页码：1175 / 1182
页数：8
相关论文
共 50 条
  • [1] The dynamics of two-electron atoms
    Briggs, JS
    AUSTRALIAN JOURNAL OF PHYSICS, 1999, 52 (03): : 341 - 349
  • [2] Two-electron photoionization of endohedral atoms
    Amusia, M. Ya.
    Liverts, E. Z.
    Mandelzweig, V. B.
    PHYSICAL REVIEW A, 2006, 74 (04):
  • [3] Two-electron atoms, ions, and molecules
    Hogaasen, Hallstein
    Richard, Jean-Marc
    Sorba, Paul
    AMERICAN JOURNAL OF PHYSICS, 2010, 78 (01) : 86 - 93
  • [4] Spectra of confined two-electron atoms
    Bielinska-Waz, D
    Karwowski, J
    Diercksen, GHF
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2001, 34 (10) : 1987 - 2000
  • [5] Two-electron atoms in strong fields
    Lambropoulos, P
    Maragakis, P
    Zhang, J
    PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1998, 305 (05): : 203 - 293
  • [6] Dynamics of entanglement for two-electron atoms
    Osenda, Omar
    Serra, Pablo
    INTERNATIONAL JOURNAL OF QUANTUM INFORMATION, 2008, 6 (02) : 303 - 316
  • [7] Three-center, two-electron bonds and atoms in molecules theory.
    Schmitz, LR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U414 - U414
  • [8] Bishomoaromatic 1,2,4-Triboracyclopentane Dianions: Strong Three-Center, Two-Electron Bonds between Three Boron Atoms
    Scheschkewitz, David
    Ghaffari, Abolfazl
    Amseis, Peter
    Unverzagt, Markus
    Subramanian, Govindan
    Hofmann, Matthias
    Schleyer, Paul Von Rague
    Schaefer, III, Henry F.
    Geiseler, Gertraud
    Massa, Werner
    Berndt, Armin
    Angewandte Chemie (International Edition in English), 2000, 39 (07): : 1272 - 1275
  • [9] Bishomoaromatic 1,2,4-triboracyclopentane dianions: Strong three-center, two-electron bonds between three boron atoms
    Scheschkewitz, D
    Ghaffari, A
    Amseis, P
    Unverzagt, M
    Subramanian, G
    Hofmann, M
    Schleyer, PV
    Schaefer, HF
    Geiseler, G
    Massa, W
    Berndt, A
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (07) : 1272 - +
  • [10] Two-electron atoms under spherical confinement
    Bhattacharyya, S.
    Saha, J. K.
    Mukhopadhyay, T. K.
    XXVIII INTERNATIONAL CONFERENCE ON PHOTONIC, ELECTRONIC AND ATOMIC COLLISIONS (ICPEAC), 2014, 488
12345