Spray deposition of exfoliated MoS2 flakes as hole transport layer in perovskite-based photovoltaics

We propose the use of solution-processed molybdenum disulfide (MoS2) flakes as hole transport layer (HTL) for metal-organic perovskite solar cells. MoS2 bulk crystals are exfoliated in 2-propanol and deposited on perovskite layers by spray coating. We fabricated cells with glass/FTO/compact-TiO2/mesoporous-TiO2/CH3NH3PbI3/spiroOMeTAD/Au structure and cells with the same structure but with MoS2 flakes as HTL instead of spiro-OMeTAD, the most widely used HTL. The electrical characterization of the cells with MoS2 as HTL show promising power conversion efficiency -eta- of 3.9% with respect to cells with pristine spiro-OMeTAD (eta=3.1%). Endurance test on 800-hour shelf life has shown higher stability for the MoS2-based cells (Delta PCE/PCE=-17%) with respect to the doped spiro-OMeTAD-based one (Delta PCE/PCE =-45%). Further improvements are expected with the optimization of the MoS2 deposition process