Crystal structure, Mossbauer spectra, and thermal behavior of H2Fe(CO)2[P(OPh)3]2

被引：13
|
作者：
Arion, V
Brunet, JJ [1 ]
Neibecker, D
机构：
[1] Univ Toulouse 3, CNRS Unite 8241, Chim Coordinat Lab, F-31077 Toulouse, France
[2] Inst Natl Polytech, F-31077 Toulouse, France
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 11期
关键词：
D O I：
10.1021/ic0006899
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first crystallographic characterization of an iron carbonyl dihydride H2Fe(CO)(2)[P(OPh)(3)](2) has been performed. The complex has a distorted octahedral geometry with two triphenylphosphite ligands trans to each other and the carbonyl ligands cis to each other. The two other equatorial sites are occupied by two cis hydrides. Mossbauer spectra and thermal behavior of H2Fe(CO)(2)[P(OPh)(3)](2) are also reported and compared with those of related complexes.
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页码：2628 / +
页数：4
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