Effect of different catalysts on the cracking of Jatropha oil

被引:28
|
作者
Biswas, Shelly [1 ,2 ]
Sharma, D. K. [1 ]
机构
[1] Indian Inst Technol Delhi, Ctr Energy Studies, New Delhi 110016, India
[2] Vel Tech Dr RR & Dr SR Tech Univ, Dept Chem, Madras 600062, Tamil Nadu, India
关键词
Cracking; Jatropha oil; Catalyst; Liquid product; CO-CRACKING; H-1-NMR SPECTROSCOPY; VACUUM RESIDUE; GASOLINE; LIQUID; BIOFUELS; FUELS;
D O I
10.1016/j.jaap.2014.10.001
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Conversion of non-edible plant seed oil Jatropha oil (JO) by cracking and the utilization of cracked liquid product obtained as a transportation fuel have gained importance. Thus, an attempt has been made to study the catalytic cracking of JO in a batch reactor. The experiments were carried out under nitrogen atmosphere at a temperature of 375 C. The catalytic cracking of JO was carried out using three catalysts ZSM-5, ZSM-5 + SiAl and NiMo/SiAl. Catalyst ZSM-5 + SiAl was the best catalyst used for JO cracking as it leads to the formation of 36% gasoline range hydrocarbons (C-7-C-11) and 58% diesel range hydrocarbons(C-12-C-22) in the cracked liquid. It was also observed that the use of catalyst had a positive effect on the pH content of the catalytically cracked liquid products. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:346 / 352
页数:7
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