Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]•2.5H2O

被引:4
|
作者
Zavakhina, M. S. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
关键词
copper; coordination polymers; metal-organic frameworks; chiral complexes; malic acid; METAL-ORGANIC FRAMEWORKS; TOPOLOGIES;
D O I
10.1134/S0022476615010151
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the interaction of basic copper carbonate with optically pure malic acid and 4,4'-bipyridine [Cu-2(S-mal)(2)(bpy)(2)(H2O)]center dot 2.5H(2)O (1) is obtained. The structure of the metal-organic coordination polymer is unique for this class of compounds, which is established by the single crystal X-ray diffraction analysis using synchrotron radiation.
引用
收藏
页码:108 / 112
页数:5
相关论文
共 50 条
  • [41] Crystal structure of [Cu2(L)2(H2O)2](SO4)2•2H2O (L = pyridoxal thiosemicarbazone)
    Rodic, Marko V.
    Leovac, Vukadin M.
    Vojinovic-Jesic, Ljiljana S.
    Cesljevic, Valerija I.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C607 - C608
  • [42] Crystal structures of three copper(II)-2,2′-bipyridine (bpy) compounds, [Cu(bpy)2(H2O)][SiF6]•4H2O, [Cu(bpy)2(TaF6)2] and [Cu(bpy)3][TaF6]2 and a related coordination polymer, [Cu(bpy)(H2O)2SnF6]n
    Nisbet, Matthew L.
    Hiralal, Emily
    Poeppelmeier, Kenneth R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 158 - +
  • [43] Synthesis, crystal structure and properties of a 3D porous coordination polymer {[Zn2(mal)2(4,4′-bipy)(H2O)2]•2(H2O)0.25}∞ (mal=malonate)
    Cao Xiang-Qian
    Chen Jin-Xiang
    Chen Yang
    Li Hong-Xi
    Ren Zhi-Gang
    Zhang Yong
    Lang Jian-Ping
    ACTA CHIMICA SINICA, 2006, 64 (24) : 2496 - 2500
  • [44] Synthesis and crystal structure of a novel tartrate copper(II) two-dimensional coordination polymer:: {[Cu2(C4H4O6)2(H2O)2]•4H2O}∞
    Jian, FF
    Zhao, PS
    Wang, QX
    JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (13) : 1133 - 1138
  • [45] Crystal structures of [Mn2(H2O)4(bpy)2(C8H12O4)2]•2H2O and [Mn(H2O)2(bpy)(C8H12O4)2/2]•H2O with bpy=2,2′-bipyridine
    Zheng, YQ
    Lin, JL
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (09): : 2201 - 2206
  • [46] Experimental and theoretical investigation of a coordination polymer [Cu(pda)(2,2′-bpy)(H2O)]n • 2nH2O
    Xie, Xiaofeng
    Chen, Sanping
    Zhai, Gaohong
    Wen, Zhengyi
    Gao, Shengli
    JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (13) : 2132 - 2141
  • [47] [Cu(bpy)(H2O)(mal)]·H2O配合物的拓扑结构及磁性研究
    金陵
    朱红林
    化学试剂, 2013, 35 (01) : 13 - 16+58
  • [48] The crystal structure of MoO2(O2)(H2O)•H2O
    Reid, Joel W.
    Kaduk, James A.
    Matei, Lidia
    POWDER DIFFRACTION, 2019, 34 (01) : 44 - 49
  • [49] Ternary copper(II) malonato complexes with alkali metals:: K2Cu(mal)2 • 3H2O, Rb2Cu(mal)2 • H2O, Cs2[Cu(H2O)2(mal)2] 2H2O
    Zheng, Yue-Qing
    Ying, Er-Bo
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (11) : 1281 - 1293
  • [50] Synthesis, crystal structure of a new tridimensional family of materials:: LnCHA(H2O)2•2.5H2O (Ln = Dy-Yb)
    Daiguebonne, C
    Guillou, O
    Gérault, Y
    Boubekeur, K
    JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 : 199 - 203