CS2.5H0.5PW12O40 bonded to an amine functionalized SiO2 as an excellent water-tolerant solid acid

被引：12
|
作者：
Horita, N
Yoshimune, M
Kamiya, Y
Okuhara, T [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Environm Sci, Sapporo, Hokkaido 0600810, Japan
[2] Natl Inst Adv Ind Sci & Technol, Res Inst Innovat Sustainable Chem, Tsukuba, Ibaraki 3058565, Japan
来源：
CHEMISTRY LETTERS | 2005年 / 34卷 / 10期
关键词：
D O I：
10.1246/cl.2005.1376
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unlike Cs2.5H0.5PW12O40, Cs2.5H0.5PW12O40-SiO2 composites combined using (3-aminopropyl)triethoxysilane are entirely insoluble and well sedimentable in reaction mixtures that contain a large excess of water. The catalytic activities for the hydration of olefin and hydrolysis of ester in the presence of excess water were comparable to those Of Cs2.5H0.5PW12O40 and were much higher than those of typical water-tolerant solid acids, such as H-ZSM-5 and Nb2O5.
引用
收藏
页码：1376 / 1377
页数：2
相关论文
共 50 条
  • [31] Rotating disk electrode study of Cs2.5H0.5PW12O40 as mesoporous support for Pt nanoparticles for PEM fuel cells electrodes
    Dsoke, S.
    Kolary-Zurowska, A.
    Zurowski, A.
    Mignini, P.
    Kulesza, P. J.
    Marassi, R.
    JOURNAL OF POWER SOURCES, 2011, 196 (24) : 10591 - 10600
  • [32] Direct benzylation of 1,3-dicarbonyl compounds catalyzed by Cs2.5H0.5PW12O40 in solvent-free conditions
    Rafiee, Ezzat
    Khodayari, Maryam
    Joshaghani, Mohammad
    CANADIAN JOURNAL OF CHEMISTRY, 2011, 89 (12) : 1533 - 1538
  • [33] Self-humidifying Cs2.5H0.5PW12O40/Nafion/PTFE composite membrane for proton exchange membrane fuel cells
    Li, MQ
    Shao, ZG
    Zhang, HM
    Zhang, YM
    Zhu, XB
    Yi, BL
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (02) : A92 - A95
  • [34] Synthesis of (S)-(-)-Propranolol by Using Cs2.5H0.5PW12O40 Nanocatalyst as Green, Eco-Friendly, Reusable, and Recyclable Catalyst
    Gharib, Ali
    Jahangir, Manouchehr
    Roshani, Mina
    Pesyan, Nader Noroozi
    Scheeren, J. W.
    Mohadesazadeh, Sara
    Lagzian, Shirin
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (03) : 350 - 355
  • [35] Cs2.5H0.5PW12O40 Encapsulated in Metal–Organic Framework UiO-66 as Heterogeneous Catalysts for Acidolysis of Soybean Oil
    Wenlei Xie
    Xinli Yang
    Pengtao Hu
    Catalysis Letters, 2017, 147 : 2772 - 2782
  • [36] Hydroisomerization of n-hexane and n-heptane over platinum-promoted Cs2.5H0.5PW12O40 (Cs2.5) studied in comparison with several other solid acids
    Liu, YY
    Koyano, G
    Misono, M
    TOPICS IN CATALYSIS, 2000, 11 (1-4) : 239 - 246
  • [37] Hydroisomerization of n-hexane and n-heptane over platinum-promoted Cs2.5H0.5PW12O40 (Cs2.5) studied in comparison with several other solid acids
    Yanyong Liu
    Gaku Koyano
    Makoto Misono
    Topics in Catalysis, 2000, 11-12 : 239 - 246
  • [38] Cs2.5H0.5PW12O40/SiO2固体酸催化剂上乙酸与烯烃的酯化和叔戊烯与甲醇的醚化
    魏民
    王海彦
    陈文艺
    复旦学报(自然科学版), 2003, (03) : 360 - 364
  • [39] Preparation and properties of titania-Cs2.5H0.5PW12O40 hybrid films
    Nakajima, Akira
    Matsui, Shunsuke
    Yanagida, Sayaka
    Kameshima, Yoshikazu
    Okada, Kiyoshi
    SURFACE & COATINGS TECHNOLOGY, 2009, 203 (09): : 1133 - 1137
  • [40] Structural studies of high dispersion H3PW12O40/SiO2 solid acid catalysts
    Newman, Andrew D.
    Brown, D. Robert
    Siril, Prem
    Lee, Adam F.
    Wilson, Karen
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (24) : 2893 - 2902
12345