Synthesis and Structural Characterization of Gallium(I) and Indium(I) Cations Coordinated by Pentamethylethylenediamine

被引：8

作者：

Glootz, Kim ^{[1
,2
]}

Kratzert, Daniel ^{[1
,2
]}

Krossing, Ingo ^{[1
,2
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, Albertstr 21, D-79104 Freiburg, Germany

[2] Univ Freiburg, FMF, Albertstr 21, D-79104 Freiburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2020年 / 646卷 / 11-12期

关键词：

Weakly coordinating anion (WCA); Subvalent gallium and indium; Main group chemistry; Structure elucidation; Coordination chemistry; UNIVALENT GALLIUM; COMPLEXES; LIGANDS; ANIONS; SALTS; CHEMISTRY; IN+;

D O I：

10.1002/zaac.202000170

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein we report on the facile access to a Ga(I)and In(I)complex salt of pentamethyldiethylenetriamine (PMDTA) with the weakly coordinating counterion [Al(ORF)(4)](-)[R-F= C(CF3)(3)]. Thus, the low temperature reaction of [M(PhF)(2)](+)(M = Ga, In) solutions in 1,2-F2C6H4(oDFB) with PMDTA yielded the title compounds M(PMDTA)(+)[Al(ORF)(4)](-)(M = Ga1, in2) in non-optimized yields. Both compounds are highly sensitive towards air and moisture, have a rather limited lifetime at room temperature, but were structurally characterized.

引用

页码：523 / 525

页数：3

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