Visible-light photoredox catalysis-enabled borocyclopropanation of alkenes

被引：6
|
作者：
Luo, Si-Si [1 ]
Shen, Hua [1 ]
Li, Shi-Jia [1 ]
Cao, Tian [1 ]
Luo, Yi-Peng [1 ]
Zhang, Shu [1 ]
Zhou, Taigang [2 ]
Liu, Xiang-Wei [1 ]
机构：
[1] Southwest Jiaotong Univ, Sichuan Engn Res Ctr Biomimet Synth Nat Drugs, Sch Life Sci & Engn, Chengdu 610031, Peoples R China
[2] Southwest Petr Univ, Coll Chem & Chem Engn, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 10期
关键词：
ASYMMETRIC CYCLOPROPANATION; INTRAMOLECULAR CYCLOPROPANATION; ENANTIOSELECTIVE HYDROBORATION; STEREOSELECTIVE-SYNTHESIS; CYCLOPROPYLBORONIC ACID; ESTERS;
D O I：
10.1039/d2qo00392a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reported herein is a convenient method for the synthesis of cyclopropyl boronates via visible-light photoredox-catalyzed borocyclopropanation of alkenes. Its wide substrate scope with regard to various substituted alkenes, good functional group tolerance, mild reaction conditions and the ease of operation all constitute the striking features of this protocol.
引用
收藏
页码：2627 / 2633
页数：7
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