Bis[hexaaquacobalt(II)] 25,26,27,28-tetrahydroxy-2,8,14,19-tetrathiacalix[4]-arene-5,11,17,23-tetrasulfonate monohydrate

被引：0
|
作者：
Akashi, Haruo [1 ]
Ichikawa, Misato [1 ]
机构：
[1] Okayama Univ Sci, Res Inst Nat Sci, Ridai, Okayama 7000005, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808011781
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the title compound, [Co(H2O)(6)](2)(C24H12O16S8) center dot H2O, the thiacalix[4]arenetetrasulfonate (= TCAS(4-)) anions adopt a cone-type conformation with an additional water molecule as a guest molecule in the hydrophobic cavity. The TCAS(4-) anions are arranged in layers in an up-down fashion. These anionic layers alternate with cationic layers consisting of rather regular octahedral cations (symmetry m). Several medium O-H center dot center dot center dot O hydrogen-bond interactions exist between the aqua ligands of the [Co(H2O)(6)] (2+) cations and the O atoms of the sulfonate groups. In addition to the two crystallographically different Co atoms, two S and four O atoms are situated on mirror planes.
引用
收藏
页码：M797 / U614
页数：12
相关论文
共 34 条
  • [21] Synthesis, conformation, and complexation of novel 25,26,27,28-tetrahydroxy-5,11:17,23-bis[[2,2′-thioxydi(o-phenylene)dithioxy]- diphenylthiolcalix[4]arene
    Yoon, K
    Kim, K
    JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (02): : 427 - 432
  • [22] 5,11,17,23-Tetra-tert-butyl-25,26,27,28-tetrakis[2-(2-chloroethoxy)ethoxy]-2,8,14,20-tetrasulfonylcalix[4]arene
    Hu, Ling
    Liu, Yang
    Ma, Jiang-Ping
    Guo, Dian-Shun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O385 - U2722
  • [23] Crystal structure of 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetrahexoxycalix[4]arene, C68H104O4
    Patel, Chintan R.
    Samipillai, Marivel
    Friedrich, Holger B.
    Kruger, Hendrik G.
    Govender, Thavendran
    Maguire, Glenn E. M.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2017, 232 (03): : 397 - 402
  • [24] Sorption Preconcentration of Eu(III) Ions from CsI Solutions by Silica Gel Impregnated with 5,11,17,23-tetrakis(diisoprpoxyphosphorylmethyl)25,26,27,28-tetrahydroxythiacalix[4]arene
    Lukashova, M. S.
    Kharchenko, S. G.
    Belikov, K. N.
    Bryleva, E. Yu
    Grebenyuk, N. N.
    Shcherbakov, I. B.
    Kalchenko, V., I
    METHODS AND OBJECTS OF CHEMICAL ANALYSIS, 2015, 10 (03): : 143 - 149
  • [25] Crystal structure of the inclusion complex 25-benzoylmethoxy-5,11,17,23tetra-tert-butyl-26,27,28-trihydroxy- 2,8,14,20-tetrathiacalix[4]arene tetraethylammonium chloride (1/1)
    Akkurt, Mehmet
    Jasinski, Jerry P.
    Mohamed, Shaahan K.
    Omran, Omran A.
    Albayati, Mustafa R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O830 - U351
  • [26] Selective extraction of Pd(II) using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra[(2-ethylthio)ethoxy]thiocalix [4]arene as extractant
    He, Jindong
    Xiong, Yanhang
    Xu, Liang
    Wang, Ling
    Yao, Dong
    Xia, Dingwu
    Tian, Yongpan
    Zhao, Zhuo
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2022, 10 (05):
  • [27] Crystal structure of 5,11,17,23-tetraacetyl-25,26,27,28-tetramethoxycalix-[4]arene dioxane hemisolvate,C40H40O8•0.5C4H8O2
    Mbemba, C
    Neuman, A
    Prangé, T
    Lecouvey, A
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (04): : 368 - 370
  • [28] Crystal structure of 5,11,17,23-tetrakis-cyanomethyl 25,26,27,28-tetrahydroxycalix[4]arene,C36H28N4O4, a test case on microcrystals using synchrotron radiation
    Lecouvey, M
    Neuman, A
    Prangé, T
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (03): : 445 - 447
  • [29] Conformational behaviour and alkali metal cation binding selectivity of 5,11,17,23-tetra-tert-butyl[25,26,27,28-tetrakis(2-pyridylmethyl)oxy]-calix[4]arene:: a molecular dynamics study
    Fantoni, AC
    Marañón, J
    CHEMICAL PHYSICS, 2000, 262 (2-3) : 359 - 368
  • [30] Lower rim substituted tert-butylcalix[4]arenes (II).: Complexing ability of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-O-(piperidinylcarbonyl)methylenecalix[4]arene.: The crystal structures of the ligand and its sodium complex
    Bochenska, M
    Zielinska, A
    Kravtsov, VC
    Gdaniec, M
    Luks, E
    Radecka-Paryzek, W
    POLYHEDRON, 2002, 21 (07) : 763 - 768
1234