Phase behavior of mixtures of ionic liquids and organic solvents

被引：14

作者：

Abildskov, Jens ^{[1
]}

Ellegaard, Martin D. ^{[1
]}

O'Connell, John P. ^{[2
]}

机构：

[1] Tech Univ Denmark, Dept Chem & Biochem Engn, CAPEC, DK-2800 Lyngby, Denmark

[2] Univ Virginia, Dept Chem Engn, Charlottesville, VA 22904 USA

来源：

JOURNAL OF SUPERCRITICAL FLUIDS | 2010年 / 55卷 / 02期

关键词：

Ionic liquids; Perturbation theory; Supercritical fluids; Fluctuation solution theory; HIGH-PRESSURE DENSITIES; PARTIAL MOLAR VOLUMES; PVT PROPERTY MEASUREMENTS; PLUS METHANOL SYSTEM; BINARY-MIXTURES; THERMODYNAMIC PROPERTIES; 1-N-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE; 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE; PHYSICAL-PROPERTIES; 1-ETHYL-3-METHYLIMIDAZOLIUM ETHYLSULFATE;

D O I：

10.1016/j.supflu.2010.10.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A corresponding-states form of the generalized van der Waals equation, previously developed for mixtures of an ionic liquid and a supercritical solute, is here extended to mixtures including an ionic liquid and a solvent (water or organic). Group contributions to characteristic parameters are implemented, leading to an entirely predictive method for densities of mixed compressed ionic liquids. Quantitative agreement with experimental data is obtained over wide ranges of conditions. Previously, the method has been applied to solubilities of sparingly soluble gases in ionic liquids and in organic solvents. Here we show results for heavier and more-than-sparingly solutes such as carbon dioxide and propane in ionic liquids. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：833 / 845

页数：13

共 50 条

[41] Regulation of Protein Folding using Organic Solvents and Ionic Liquids
Hidaka, Yuji
Nishimura, Ryosuke
Shimamoto, Shigeru
BIOPHYSICAL JOURNAL, 2017, 112 (03) : 57A - 57A
[42] Phase Behavior of Aqueous Biphasic Systems Composed of Ionic Liquids and Organic Salts
Gao, Jing
Chen, Li
Yan, Zongcheng
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (03): : 464 - 470
[43] Evaluation of COSMO-RS model in binary and ternary mixtures of natural antioxidants, ionic liquids and organic solvents
Alevizou, Efthimia I.
Voutsas, Epaminondas C.
FLUID PHASE EQUILIBRIA, 2014, 369 : 55 - 67
[44] New prospects on solvothermal carbonisation assisted by organic solvents, ionic liquids and eutectic mixtures-A critical review
Mruthunjayappa, Manohara Halanur
Sanna Kotrappanavar, Nataraj
Mondal, Dibyendu
PROGRESS IN MATERIALS SCIENCE, 2022, 126
[45] Comparative screening of organic solvents, ionic liquids, and their binary mixtures for vitamin E extraction from deodorizer distillate
Qin, Hao
Song, Zhen
Qi, Zhiwen
Sundmacher, Kai
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2022, 171
[46] Pretreatment of Pussy Willow and Korean Pine Using Various Ionic Liquids and their Mixtures with Organic Solvents for Enzymatic Saccharification
Han, Song-Yi
Park, Chan-Woo
Lee, Eun-Ah
Park, Ji-Soo
Kwon, Gu-Joong
Kim, Nam-Hun
Lee, Seung-Hwan
BIORESOURCES, 2021, 16 (01) : 455 - 469
[47] Ionic Liquids and Deep Eutectic Solvents in Natural Products Research: Mixtures of Solids as Extraction Solvents
Dai, Yuntao
van Spronsen, Jaap
Witkamp, Geert-Jan
Verpoorte, Robert
Choi, Young Hae
JOURNAL OF NATURAL PRODUCTS, 2013, 76 (11): : 2162 - 2173
[48] Electrogenerated NHCs in Organic Synthesis: Ionic Liquids vs Organic Solvents Effects
Vetica, Fabrizio
Bortolami, Martina
Petrucci, Rita
Rocco, Daniele
Feroci, Marta
CHEMICAL RECORD, 2021, 21 (09): : 2130 - 2147
[49] Phase equilibria of mixtures of mutually immiscible ionic liquids
Arce, Alberto
Earle, Martyn J.
Katdare, Suhas P.
Rodriguez, Hector
Seddon, Kenneth R.
FLUID PHASE EQUILIBRIA, 2007, 261 (1-2) : 427 - 433
[50] The Solvent Selection framework: solvents for organic synthesis, separation processes and ionic liquids solvents
Mitrofanov, Igor
Sansonetti, Sascha
Abildskov, Jens
Sin, Gurkan
Gani, Rafiqul
22 EUROPEAN SYMPOSIUM ON COMPUTER AIDED PROCESS ENGINEERING, 2012, 30 : 762 - 766

← 1 2 3 4 5 →