Temperature-assisted rapid nucleation: a facile method to optimize the film morphology for perovskite solar cells

The nucleation stage has an important influence on the lead halide perovskite film morphology, and therefore the solar cell performance. Here, we introduce a facile temperature-assisted rapid nucleation (TRN) method to improve the film crystallization process and the film morphology. By employing low temperature anti-solvents (diethyl ether, chlorobenzene and toluene), we stimulate homogeneous nuclei growth, resulting in a highly dense perovskite thin layer. The TRN method prepared (FAPbI(3))(0.85)(MAPbBr(3))(0.15) devices exhibit a power conversion efficiency up to 19.2% and maintain over 85% of the original efficiency after 40 days of storage at room temperature under a relative humidity of 10-40%.