(5-Carboxy-1H-pyrazole-3-carboxylato-κ2N2,O3)bis(1,10-phenanthroline-κ2 N,N′)cobalt(III) perchlorate 2.5-hydrate

被引：5

作者：

Xie, Hui-Dong ^{[1
]}

Xie, Cheng-Zhi ^{[1
]}

Wang, Xiao-Qing ^{[1
]}

Shen, Guang-Qiu ^{[1
]}

Shen, De-Zhong ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807018703

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title mononuclear complex, [Co(C5H2N2O4)( C12H8N2) 2] ClO4 center dot 2.5H(2)O, the Co-III atom is in a slightly distorted octahedral environment, coordinated by four N atoms from two N, N'-bidentate phenanthroline ligands, and one O and one N atom of the 5-carboxy-1H-pyrazole-3carboxylate ligand. The molecules are linked into a three-dimensional framework by O-H . . . O hydrogen bonds and pi-pi interactions.

引用

页码：M1477 / M1479

页数：3

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