Polyethylene glycol (PEG) as a green solvent for carbon-carbon bond formation reactions

被引:103
|
作者
Vafaeezadeh, Majid [1 ]
Hashemi, Mohammad Mahmoodi [1 ]
机构
[1] Sharif Univ Technol, Dept Chem, Tehran, Iran
关键词
Polyethylene glycol; PEG; Coupling reactions; Green solvent; Carbon-carbon bond formation; CATALYZED N-ARYLATION; CROSS-COUPLING REACTIONS; RECYCLABLE REACTION MEDIUM; ACIDIC IONIC LIQUID; POLY(ETHYLENE GLYCOL); ARYL HALIDES; PALLADIUM CATALYST; ATOM-EFFICIENT; HECK REACTION; ADIPIC ACID;
D O I
10.1016/j.molliq.2015.03.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, polyethylene glycol (PEG) has attracted special attention as a green and inexpensive solvent in various chemical transformations. The current critical review deals with breakthrough achievements for the applications of PEG as an alternative reaction media well-known coupling reactions such as Suzuki, Heck, Stille, Sonogashira, Hiyama and some challenging organic reactions for carbon-carbon bond formation. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:73 / 79
页数:7
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