Nanospherical Cu2O/NiO synthesized by electrochemical dealloying as efficient electrode materials for supercapacitors

被引:12
|
作者
Miao, Yidong [1 ]
Zhang, Xuping [2 ]
Sui, Yanwei [2 ]
Hu, Enyuan [2 ]
Qi, Jiqiu [2 ]
Wei, Fuxiang [2 ]
Meng, Qingkun [2 ]
He, Yezeng [2 ]
Sun, Zhi [2 ]
Ren, Yaojian [2 ]
Zhan, Zhenzhen [2 ]
机构
[1] China Univ Min & Technol, Xuzhou 221116, Jiangsu, Peoples R China
[2] China Univ Min & Technol, Sch Mat Sci & Phys, Xuzhou 221116, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanosphere; Cu2O/NiO; Supercapacitors; Electronic materials; Microstructure; PERFORMANCE; FABRICATION;
D O I
10.1016/j.matlet.2020.127300
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, Cu2O/NiO with nanosphere structure has been successfully synthesized by dealloying a copper foil coated with Zn-Cu-Ni alloy films. First, Zn-Ni films were electrodeposited on copper foil. Next, the Zn-Cu-Ni films were produced by annealing and the Cu2O/NiO was obtained after Zn-dealloying and oxidation. Due to the advantage of the tunable nanosphere structure and dealloying synthesis method, Cu2O/NiO has excellent supercapacitor properties, such as excellent cycling stability (94.5% after 5000 cycles) and high specific capacitance (2255.5 mF/cm(2) in 1 mA/cm(2)). These data suggested that this low-cost oxide Cu2O/NiO with nanosphere morphology synthesized by dealloying method could be a promising electrode material for supercapacitors. (C) 2020 Published by Elsevier B.V.
引用
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页数:5
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