New chiral aminophosphine carboxyphosphinite ligands (AMPCP). Synthesis and application in asymmetric hydrogenation and hydroformylation

被引：15

作者：

Naili, S ^{[1
]}

Mortreux, A ^{[1
]}

Agbossou, F ^{[1
]}

机构：

[1] Univ Sci & Technol Lille, ENSC Lille, Catalyse Heterogene & Homogene Lab, UPRESA 8010,Grp Chim Organ Appliquee, F-59652 Villeneuve Dascq, France

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 19期

关键词：

D O I：

10.1016/S0957-4166(98)00363-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the first three aminophosphine-carboxyphosphinite diphosphanes derived directly from alpha-amino acids is presented. These ligands were applied in the asymmetric hydrogenation of dihydro-2,4-dimethyl-2,3-furandione giving the corresponding pantolactone with up to 42% ee. They were also involved, in association with platinum, in the asymmetric hydroformylation of styrene giving the branched aldehyde with low ee (<5%). (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3421 / 3430

页数：10

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