Obtainment and Comparative Study of Electrochemical Behavior of Composite Electrodes Based on Polyaniline and Its N-Substituted Derivatives

被引：4
|
作者：
Abalyaeva, V. V. [1 ]
Nikolaeva, G. V. [1 ]
Kabachkov, E. N. [1 ,3 ]
Kiseleva, S. G. [2 ]
Orlov, A. V. [2 ]
Efimov, O. N. [1 ]
Karpacheva, G. P. [2 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
[2] Russian Acad Sci, Topchiev Intstitute Petrochem Synth, Moscow 119991, Russia
[3] Russian Acad Sci, Chernogolovka Sci Ctr, Chernogolovka 142432, Moscow Oblast, Russia
来源：
POLYMER SCIENCE SERIES B | 2018年 / 60卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
GRAPHENE OXIDE; CARBON; NANOCOMPOSITES; MORPHOLOGY; OXIDATION; ANILINE; SURFACE; FILM;
D O I：
10.1134/S1560090418060015
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hybrid polymer nanomaterials based on N-substituted polyanilines and graphene oxide are synthesized for the first time via the in situ oxidative polymerization of 3,6-dianiline-2,5-dichloro-1,4-benzoquinone and 3,6-phenylenediamine-2,5-dichloro-1,4-benzoquinone in the presence of graphene oxide. The morphology and electrochemical properties of composite electrodes made of graphite foil support covered with polyaniline (or nanocomposites based on its derivatives containing the polyaniline chain with electroactive N-substituents and graphene oxide) coating are studied. It is shown that the electroconductive nanocomposite material characterized by the electrochemical capacitance above 1000 F/g and the stability of capacitive characteristics under prolonged charge/discharge cycles in a proton (1M H2SO4) electrolyte is formed on the graphite foil support.
引用
收藏
页码：780 / 788
页数：9
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