Densities and Viscosities of the Binary Mixtures of Phenylmethanol with 2-Butanone

被引:21
|
作者
Habibullah, M. [1 ]
Rahman, Ismail M. M. [1 ,2 ]
Uddin, M. Ashraf [1 ]
Iwakabe, Koichi [3 ]
Azam, Anisul [1 ]
Hasegawa, Hiroshi [2 ]
机构
[1] Univ Chittagong, Dept Chem, Fac Sci, Chittagong 4331, Bangladesh
[2] Kanazawa Univ, Grad Sch Nat Sci & Technol, Kanazawa, Ishikawa 9201192, Japan
[3] Mitsui Chem Inc, Proc Technol Ctr, Chiba 2990265, Japan
来源
关键词
ALCOHOL PLUS 2-PHENYLETHANOL; BENZYL ALCOHOL; KINEMATIC VISCOSITY; REFRACTIVE-INDEXES; SURFACE TENSIONS; TERNARY MIXTURES; LIQUID MIXTURES; VISCOUS-FLOW; 318.15; K; TEMPERATURES;
D O I
10.1021/je200150r
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities of the binary systems of phenylmethanol with 2-butanone were measured for the entire composition range at T = (303.15, 308.15, 313.15, 318.15, and 323.15) K and at the atmospheric pressure. The excess molar volumes were derived from the experimental data and were fitted with the Redlich-Kister equation to obtain their coefficients and standard deviations. The Grunberg-Nissan equation was used to correlate the viscosity data. Furthermore, kinematic viscosities were compared with those predicted by the UNIFAC-VISCO model. The cause of relatively large deviations between the experimental and predicted kinematic viscosities was explored by comparing the combinatorial and residual terms of the UNIFAC-VISCO model.
引用
收藏
页码:3323 / 3327
页数:5
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