Alkynyl sulfides as dienophiles in cobalt-catalyzed Diels-Alder reactions

被引：16
|
作者：
Hilt, G [1 ]
Lüers, S [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
SYNTHESIS-STUTTGART | 2003年 / 12期
关键词：
alkynes; catalysis; cobalt; Diels-Alder reactions; sulfides; ACYCLIC 1,3-DIENES; SULFOXIDES; PRECURSOR;
D O I：
10.1055/s-2003-41034
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cobalt(I)-catalyzed cycloaddition of alkynyl sulfides with 1,3-dienes can be realized at ambient temperatures. In combination with a mild oxidation step various polysubstituted and functionalised diaryl sulfides can be synthesized in good overall yields.
引用
收藏
页码：1784 / 1786
页数：3
相关论文
共 50 条
  • [21] Fluorous dienophiles are powerful diene scavengers in Diels-Alder reactions
    Werner, S
    Curran, DP
    ORGANIC LETTERS, 2003, 5 (18) : 3293 - 3296
  • [22] Theoretical study of the Diels-Alder reactions of benzene with fluorinated dienophiles
    Zdravkovski, Z
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2004, 684 (1-3): : 99 - 102
  • [23] DIELS-ALDER REACTIONS WITH 2-CARBON SULFUR DIENOPHILES
    WENKERT, E
    BROKA, CA
    FINNISH CHEMICAL LETTERS, 1984, (4-5): : 126 - 129
  • [24] Theoretical Study on the Diels-Alder Reactions Between Germabenzenes and Dienophiles
    Wang Yan
    Zeng Xiao-Lan
    Fang De-Cai
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2010, 31 (01): : 106 - 111
  • [25] Theoretical predication of Diels-Alder reactions of highly strained dienophiles
    Zhang, Congjie
    Jiao, Hui
    Jia, Wenhong
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2020, 1175
  • [26] THIOIMIDATES AS DIENOPHILES IN DIELS-ALDER REACTIONS WITH INVERSE ELECTRON DEMAND
    OVERHEU, W
    SEITZ, G
    WASSMUTH, H
    CHEMIKER-ZEITUNG, 1989, 113 (05): : 188 - 190
  • [27] Tricarbonyls: Reactive model dienophiles for asymmetric Diels-Alder reactions
    Lehmler, HJ
    Nieger, M
    Breitmaier, E
    SYNTHESIS-STUTTGART, 1996, (01): : 105 - +
  • [28] THE DIELS-ALDER REACTION OF PYRIDAZINONES AS DIENOPHILES
    MATYUS, P
    FUJI, K
    TANAKA, K
    HETEROCYCLES, 1993, 36 (09) : 1975 - 1978
  • [29] Fluoropropenoates as dienophiles in the Diels-Alder reaction
    Patrick, Timothy B.
    Fianu, Cynthia
    Pak, Eric
    Zaksas, Kasey
    Neal, Bradley E.
    JOURNAL OF FLUORINE CHEMISTRY, 2006, 127 (07) : 861 - 864
  • [30] Regiodivergent Cobalt-Catalyzed Diels-Alder Reactions for the Synthesis of Bifunctional Building Blocks and Their Suzuki-Cross-Coupling Polymerizations
    Kuttner, Julian R.
    Hilt, Gerhard
    MACROMOLECULES, 2014, 47 (16) : 5532 - 5541
12345