Alkynyl sulfides as dienophiles in cobalt-catalyzed Diels-Alder reactions

被引：16
|
作者：
Hilt, G [1 ]
Lüers, S [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
SYNTHESIS-STUTTGART | 2003年 / 12期
关键词：
alkynes; catalysis; cobalt; Diels-Alder reactions; sulfides; ACYCLIC 1,3-DIENES; SULFOXIDES; PRECURSOR;
D O I：
10.1055/s-2003-41034
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cobalt(I)-catalyzed cycloaddition of alkynyl sulfides with 1,3-dienes can be realized at ambient temperatures. In combination with a mild oxidation step various polysubstituted and functionalised diaryl sulfides can be synthesized in good overall yields.
引用
收藏
页码：1784 / 1786
页数：3
相关论文
共 50 条
  • [1] The first broad application of alkynyl sulfides as dienophiles in cobalt(I)-catalyzed Diels-Alder reactions
    Hilt, G
    Lüers, S
    Harms, K
    JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (03): : 624 - 630
  • [2] Alkynylboronic esters as efficient dienophiles in cobalt-catalyzed Diels-Alder reactions
    Hilt, G
    Smolko, KI
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (24) : 2795 - 2797
  • [3] COBALT-CATALYZED INTRAMOLECULAR HOMO DIELS-ALDER REACTIONS
    LAUTENS, M
    TAM, W
    EDWARDS, LG
    JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (01): : 8 - 9
  • [4] meta-directing cobalt-catalyzed Diels-Alder reactions
    Hilt, Gerhard
    Janikowski, Judith
    Hess, Wilfried
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (31) : 5204 - 5206
  • [5] OXAZOLES AS DIENOPHILES IN DIELS-ALDER REACTIONS
    DONDONI, A
    FOGAGNOLO, M
    MASTELLARI, A
    PEDRINI, P
    UGOZZOLI, F
    TETRAHEDRON LETTERS, 1986, 27 (33) : 3915 - 3918
  • [6] Cobalt-catalyzed versus uncatalyzed intramolecular Diels-Alder cycloadditions
    Biletskyi, Bohdan
    Tenaglia, Alphonse
    Clavier, Herve
    TETRAHEDRON LETTERS, 2018, 59 (02) : 103 - 107
  • [7] Lewis acid catalyzed Diels-Alder reactions of highly hindered dienophiles
    Hubbard, RD
    Miller, BL
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (12): : 4143 - 4146
  • [8] DIELS-ALDER REACTIONS WITH N=N DIENOPHILES
    MEYER, P
    KASPER, F
    ZEITSCHRIFT FUR CHEMIE, 1982, 22 (09): : 348 - 348
  • [9] Diels-Alder reactions of diaryl thioketones with dienophiles
    Rapp, J.
    Huisgen, R.
    Tetrahedron, 53 (03):
  • [10] Diels-Alder Reactions between Silabenzenes and Dienophiles
    Wang Yan
    Zeng Xiao-Lan
    Wang Ling
    ACTA PHYSICO-CHIMICA SINICA, 2009, 25 (02) : 371 - 376
12345