tert-Butyl Nitrite (TBN) as a Versatile Reagent in Organic Synthesis

被引：82
|
作者：
Li, Pengfei [1 ]
Jia, Xiaodong [1 ,2 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Anning East Rd 967, Lanzhou 730070, Gansu, Peoples R China
[2] Yangzhou Univ, Sch Chem & Chem Engn, Siwangting Rd 180, Yangzhou 225002, Jiangsu, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2018年 / 50卷 / 04期
关键词：
tert-butyl nitrite; nitrosation; oximation; diazotization; nitration; oxidation; SANDMEYER TRIFLUOROMETHYLATION; AEROBIC OXYNITRATION; CATALYTIC-SYSTEM; SECONDARY-AMINES; N-NITROSOAMIDES; METAL; ALKENES; CONVERSION; OXIDATION; NITRATION;
D O I：
10.1055/s-0036-1589155
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
tert-Butyl nitrite (TBN) is an important metal-free reagent that is widely applied in various organic transformations. Besides its traditional applications in nitrosation and diazotization, its ability to activate molecular oxygen to enable the initiation of radical reactions, including nitration, oximation, oxidation, and so on, has attracted extensively attention in the past decade. This review highlights recent advances in this field to promote further exploration of this versatile compound. 1 Introduction 2 Reactions Involving TBN 2.1 Nitrosation 2.2 Oximation 2.3 Diazotization 2.4 Nitration 2.5 Oxidation 2.6 Other Reactions 3 Conclusion and Perspective
引用
收藏
页码：711 / 722
页数：12
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