A four-fold interpenetrated metal-organic framework as a fluorescent sensor for volatile organic compounds

被引：57

作者：

Zhao, Xiaoyu ^{[1
,2
]}

Li, Yang ^{[1
,2
]}

Chang, Ze ^{[3
,4
]}

Chen, Long ^{[1
,2
,4
]}

Bu, Xian-He ^{[3
,4
]}

机构：

[1] Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China

[2] Tianjin Univ, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300072, Peoples R China

[3] Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, TKL Met & Mol Based Mat Chem, Tianjin 300350, Peoples R China

[4] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 38期

基金：

中国国家自然科学基金;

关键词：

AGGREGATION-INDUCED EMISSION; TURN-ON FLUORESCENCE; COORDINATION POLYMERS; LUMINESCENT SENSOR; AQUEOUS-SOLUTION; CARBON-DIOXIDE; MOLECULES; LIGAND; MOF; TEMPERATURE;

D O I：

10.1039/c6dt02169g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A four-fold interpenetrated three dimensional (3D) metal-organic framework, [Cd-2(tppe)(bpdc)(2)(H2O)]center dot solvent (1), was synthesized with a tetraphenylethene (TPE)-based ligand, 1,1,2,2-tetrakis(4-(pyridin-4-yl) phenyl) ethene (TPPE). This complex exhibits intense blue luminescence and is sensitive to toxic volatile organic compounds (VOCs).

引用

页码：14888 / 14892

页数：5

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