Binuclear N8 28-membered macrocyclic transition metal complexes:: Synthesis and characterization

被引：8
|
作者：
Nasman, OSM
机构：
[1] Department of Chemistry, Al-Azhar University of Gaza
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2001年 / 31卷 / 08期
关键词：
D O I：
10.1081/SIM-100107208
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel family of tetraimineoctaaza macrocyclic complexes [M2LX3]X, (M = Co(II), Ni(II), Cu(II) and Zn(II); X = Cl or Br) has been prepared by the condensation reaction of triethylenetetramine with phthalaldehyde in methanol in the presence of metal ions as templates. The complexes have been characterized on the bases of elemental analyses, 1R, H-1 NMR and UV-Vis spectroscopic studies, as well as conductivity and magnetic susceptibility data. The coordination geometry around the metal ions is octahedral in which a single halogen bridges the two metal ions.
引用
收藏
页码：1433 / 1442
页数：10
相关论文
共 50 条
  • [31] The synthesis and characterization of a new polyamidoxime and its transition metal complexes containing 17-membered two-fold macrocyclic moieties
    Gok, Y
    NEW JOURNAL OF CHEMISTRY, 1996, 20 (09) : 971 - 977
  • [32] The synthesis and characterization of new polyamidoxime and its transition metal complexes containing 17-membered two-fold macrocyclic moieties
    New Journal of Chemistry, 20 (09):
  • [33] Synthesis and Characterization of Two Binuclear Macrocyclic Zinc(Ⅱ) Complexes by Anion Exchange
    欧光川
    黄中文
    潘泽毅
    周东来
    袁先友
    结构化学, 2014, 33 (06) : 903 - 908
  • [34] Synthesis, spectral, thermal and antimicrobial studies of transition metal complexes of 14-membered tetraaza[N4] macrocyclic ligand
    Shankarwar, Sunil G.
    Nagolkar, Bhagwat B.
    Shelke, Vinod A.
    Chondhekar, Trimbak K.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 145 : 188 - 193
  • [35] Cd(II) complexes with N8 and N4O4 donor macrocyclic ligands
    Fernandez-Fernandez, M. del Carmen
    Bastida, Rufina
    Macias, Alejandro
    Perez-Lourido, Paulo
    Valencia, Laura
    INORGANICA CHIMICA ACTA, 2009, 362 (02) : 471 - 476
  • [36] Synthesis and characterization of binuclear transition metal rhenium(VII) complexes with bridging cyanide ligands
    Goncalves, IS
    Kuhn, FE
    Lopes, AD
    Parola, AJ
    Pina, F
    Sotomayor, J
    Romao, CC
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 560 (1-2) : 117 - 124
  • [37] Binuclear transition metal complexes of bicompartmental SNO donor ligands: synthesis, characterization, and electrochemistry
    Kulkarni, Naveen V.
    Sathisha, M. P.
    Budagumpi, Srinivasa
    Kurdekar, Gurunath S.
    Revankar, Vidyanand K.
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (08) : 1451 - 1461
  • [38] TRANSITION-METAL COMPLEXES OF 20-22-MEMBERED OCTAAZAMACROCYCLES - SYNTHESIS AND CHARACTERIZATION
    SHAKIR, M
    VARKEY, SP
    NASMAN, OSM
    POLYHEDRON, 1995, 14 (10) : 1283 - 1288
  • [39] Synthesis and characterization of new 13 and 14-membered macrocycles and their transition metal complexes
    Nishat, N
    Rahis-ud-din
    Haq, MM
    Siddiqi, KS
    TRANSITION METAL CHEMISTRY, 2003, 28 (08) : 948 - 953
  • [40] Synthesis and characterization of new 13 and 14-membered macrocycles and their transition metal complexes
    Nahid Nishat
    Mohammad M. Rahis-ud-din
    Khwaja S. Haq
    Transition Metal Chemistry, 2003, 28 (8) : 948 - 953
12345