Mild and efficient method for the cleavage of cyclic and acyclic ethers by iodine under solvent-free conditions

被引：27
|
作者：
Yadav, JS [1 ]
Reddy, BVS [1 ]
Reddy, PMK [1 ]
Gupta, MK [1 ]
机构：
[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 49期
关键词：
ethers; acyl chloride; iodine;
D O I：
10.1016/j.tetlet.2005.10.017
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ethers undergo smooth cleavage with acyl chlorides in the presence of a catalytic amount of elemental iodine under extremely mild conditions to give the corresponding halo esters. This new procedure offers significant advantages such as high conversions, short reaction times and enhanced selectivity together with mild reaction conditions, which makes it an attractive strategy. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8493 / 8495
页数：3
相关论文
共 50 条
  • [21] Iodination of aromatic compounds under mild and solvent-free conditions
    Hajipour, AR
    Ruoho, AE
    ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2002, 34 (06) : 647 - 651
  • [22] Efficient Synthesis of Ferrocenylcyclohexenone Under Solvent-Free Conditions
    Shen, Zhi-Liang
    Zhou, Wei-Juan
    Yang, Jin-Ming
    Ji, Shun-Jun
    SYNTHETIC COMMUNICATIONS, 2009, 39 (21) : 3924 - 3933
  • [23] Iodine-Catalyzed Synthesis of Five-Membered Cyclic Ethers from 1,3-Diols under Solvent-Free Conditions
    Kasashima, Yoshio
    Uzawa, Atsushi
    Nishida, Tadasuke
    Mino, Takashi
    Sakamoto, Masami
    Fujita, Tsutomu
    JOURNAL OF OLEO SCIENCE, 2009, 58 (08) : 421 - 427
  • [24] An efficient and novel method for the synthesis of β-aroylpropionic acids under solvent-free conditions
    Mogilaiah, K
    Reddy, NV
    Reddy, GR
    SYNTHETIC COMMUNICATIONS, 2003, 33 (18) : 3109 - 3113
  • [25] An Efficient Method for the Synthesis of Isoxazolines Under Microwave Irradiation and Solvent-Free Conditions
    Patil, Pravin O.
    Bari, Sanjay B.
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (07) : 3588 - 3590
  • [26] An efficient and novel method for the synthesis of aromatic sulfones under solvent-free conditions
    Hajipour, AR
    Mallakpour, SE
    Imanzadeh, G
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2001, 40 (03): : 237 - 239
  • [27] An efficient and novel method for the synthesis of sulfinate esters under solvent-free conditions
    Hajipour, AR
    Falahati, AR
    Ruoho, AE
    TETRAHEDRON LETTERS, 2006, 47 (16) : 2717 - 2719
  • [28] Mild and efficient barbier allylation reaction mediated by magnesium powder under solvent-free conditions
    Li, Shunxi
    Wang, Jin-Xian
    Wen, Xiaoliu
    Ma, Xiaofang
    TETRAHEDRON, 2011, 67 (05) : 849 - 855
  • [29] Preparation of silyl ethers using hexamethyidisilazane in the presence of N-bromosuccinimide under mild and solvent-free conditions
    Shaterian, Hamid Reza
    Doostmohammadi, Razieh
    Ghashang, Majid
    CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (09) : 1709 - 1714
  • [30] Mesoporous Zirconium Oxophosphate: An Efficient Catalyst for the Synthesis of Cyclic Acetals and Cyclic Carbonates under Solvent-Free Conditions
    Islam, Sk. Safikul
    Bhanja, Piyali
    Ghosh, Kajari
    Molla, Rostam Ali
    Yasmin, Nasima
    Das, Debasis
    Islam, Sk. Manirul
    CHEMISTRYSELECT, 2017, 2 (32): : 10595 - 10602
12345