Fischer-Tropsch synthesis: evidence for chain initiation by ethene and ethanol for an iron catalyst

被引：23

作者：

Shi, BC ^{[1
]}

Davis, BH ^{[1
]}

机构：

[1] Univ Kentucky, Ctr Appl Energy Res, Lexington, KY 40511 USA

来源：

TOPICS IN CATALYSIS | 2003年 / 26卷 / 1-4期

关键词：

mechanism; chain initiation; Fischer-Tropsch synthesis; isotopic tracer; C-14;

D O I：

10.1023/B:TOCA.0000012996.87917.cd

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

C-14-labeled ethene, propene and ethanol have been added to the synthesis gas feed to cobalt and iron Fischer - Tropsch catalysts operated in the slurry phase. Oxidation to convert the carbon in the 1-position of alkene products to CO2 was carried out. Results from oxidation of 1-C-14-1-hexene were used to document the suitability of the approach. The C-14 content of CO2 was at or below the detection limit in the Fischer - Tropsch synthesis product, showing for ethene that incorporation by termination could not account for the results. The data are consistent with the added alkene or alcohol serving to initiate chain growth.

引用

页码：157 / 161

页数：5

共 50 条

[41] Development of iron supported carbon foam catalyst for Fischer-Tropsch synthesis
Huang, Jielang
Zhu, Zongbo
Zhang, Dandan
Li, Xiaoguo
Hou, Zhanggui
Zhang, Yi
REACTION KINETICS MECHANISMS AND CATALYSIS, 2022, 135 (05) : 2457 - 2473
[42] Fischer-Tropsch Synthesis: Compositional Modulation Study using an Iron Catalyst
van Vuuren, Matthys Janse
Davis, Burtron H.
FISCHER-TROPSCH SYNTHESIS, CATALYSTS AND CATALYSIS, 2006, 163 : 201 - 215
[43] The Use of Iron Ore as a Catalyst in Fischer-Tropsch Synthesis-A Review
Okoye-Chine, Chike George
Mubenesha, Samuel
CRYSTALS, 2022, 12 (10)
[44] STUDIES OF FISCHER-TROPSCH SYNTHESIS OVER A FUSED IRON CATALYST.
Dictor, Ronald A.
Bell, Alexis T.
1600, (20): : 1 - 2
[45] NEW IRON-NICKEL ALLOY CATALYST FOR FISCHER-TROPSCH SYNTHESIS
COOPER, ME
FROST, J
APPLIED CATALYSIS, 1990, 57 (02): : L5 - L8
[46] ε-Iron carbide as a low-temperature Fischer-Tropsch synthesis catalyst
Xu, Ke
Sun, Bo
Lin, Jun
Wen, Wen
Pei, Yan
Yan, Shirun
Qiao, Minghua
Zhang, Xiaoxin
Zong, Baoning
NATURE COMMUNICATIONS, 2014, 5
[47] Catalytic performance of an iron-based catalyst in Fischer-Tropsch synthesis
Sarkari, Majid
Fazlollahi, Farhad
Ajamein, Hossein
Atashi, Hossein
Hecker, William C.
Baxter, Larry L.
FUEL PROCESSING TECHNOLOGY, 2014, 127 : 163 - 170
[48] Partially hydrated iron–chromium oxide catalyst for the Fischer-Tropsch synthesis
Alexander A. Khassin
Anatolii G. Sipatrov
Margarita P. Demeshkina
Tatyana P. Minyukova
Reaction Kinetics and Catalysis Letters, 2009, 97 : 371 - 379
[49] Effect of Hydrothermal Treatment on Precipitated Iron Catalyst for Fischer-Tropsch Synthesis
Ma, Cailian
Chen, Jiangang
CATALYSIS LETTERS, 2015, 145 (02) : 702 - 711
[50] IMPROVING OF SELECTIVITY OF CATALYST OF FISCHER-TROPSCH SYNTHESIS
KOTOWSKI, W
RESZKA, J
PRZEMYSL CHEMICZNY, 1981, 60 (02): : 79 - 82

← 1 2 3 4 5 →