X-ray crystal structure and properties of the [Mo(CN)2O(acetam)]•2.5H2O complex

被引：7

作者：

Midura, A ^{[1
]}

Szklarzewicz, J ^{[1
]}

Lasocha, W ^{[1
]}

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

TRANSITION METAL CHEMISTRY | 2003年 / 28卷 / 08期

关键词：

D O I：

10.1023/A:1026386905457

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray crystal structure and properties of the [Mo(CN)(2)O(acetam)] . 2.5H(2)O {acetam = N-[1-(pyridin-2-yl)ethylidene] diethanetriamine} complex are described. The complex was prepared by the in situ reaction of [Mo(CN)(4)O(H2O)](2-), 2-acetylpyridine and diethylenetriamine in aqueous solution. The complex is seven coordinated. The Mo atom having a distorted pentagonal bipyramid arrangement with a tetradentate 'half-unit' Schiff base and oxygen ligand in a plane. The properties of the salt, i. r., u. v.-vis. spectra and cyclic voltammetry measurements are described and compared with those of [Mo(CN)(2)O(diaceen)] . H2O {diaceen = N, N'-bis[1( pyridin-2-yl) ethylidene] ethane-1,2-diamine) having the same coordination number for the metal.

引用

页码：918 / 924

页数：7

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