Asymmetric methoxyselenenylation of alkyl vinyl ethers: a new route to chiral acetals

被引：20
|
作者：
Uchiyama, M [1 ]
Satoh, S [1 ]
Ohta, A [1 ]
机构：
[1] Tokyo Univ Pharm & Life Sci, Sch Pharm, Tokyo 1920392, Japan
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 08期
关键词：
chiral selenium compounds; asymmetric methoxyselenenylation; vinyl ethers; chiral acetals;
D O I：
10.1016/S0040-4039(00)02285-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The asymmetric methoxyselenenylation of alkyl vinyl ethers afforded the corresponding chiral acetals with moderate to good diastereoselectivity. This reaction and subsequent deselenenylation provided a new method of preparing enantiomerically enriched acetals in which the acetal carbon was the only stereogenic center. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：1559 / 1562
页数：4
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