Oxidation of organic pollutants of water to mineralization by catalytic ozonation

被引：29
|
作者：
Fontanier, V
Farines, V
Albet, J
Baig, S
Molinier, J
机构：
[1] INRA, UMR 31A1010, Lab Chim Agroind, Ensiacet,Equipe Genie Chim, F-31077 Toulouse, France
[2] Degremont SA, Rueil Malmaison, France
来源：
OZONE-SCIENCE & ENGINEERING | 2005年 / 27卷 / 02期
关键词：
ozone; catalytic ozonation; organic pollutants; TOC removal; TOCCATA process;
D O I：
10.1080/01919510590925239
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The oxidation of various organic compounds in aqueous solution was studied using catalytic ozonation (TOCCATA process) and conventional ozonation. The aim of the work is to assess catalytic ozonation efficiency for the mineralization of various organic compounds in order to envisage its application on real effluents. The selected organic compounds (about 30) are commonly found in industrial wastewaters. Comparative experiments were performed in batch mode at laboratory scale. Investigations were focused on ozone consumption rate, variations of total organic carbon, oxidation by-products and oxidation rate. Catalytic and conventional ozonation treatments were compared considering kinetic data, mineralization extent, and effect of organic functionalities. Catalytic ozonation system according to the TOCCATA process was able to convert organic compounds which were totally inert to ozone treatment and permitted considerably enhanced reaction rates when compounds were reactive to ozonation.
引用
收藏
页码：115 / 128
页数：14
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