机构:
Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USALos Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA
Chitanvis, SM
[1
]
机构:
[1] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA
来源:
PHYSICAL REVIEW E
|
2001年
/
63卷
/
02期
关键词:
D O I:
暂无
中图分类号:
O35 [流体力学];
O53 [等离子体物理学];
学科分类号:
070204 ;
080103 ;
080704 ;
摘要:
We have mapped the physics of polymer melts onto a time-dependent Landau-Ginzburg \psi\(4) field theory using techniques of functional integration. Time in the theory is simply a label fur the location of a given monomer along the extent of a flexible chain. With this model, one can show that the limit of infinitesimal concentration of a polymer melt corresponds to a dynamic critical phenomenon. The transition to the entangled stare is also shown to be a critical point. For larger concentrations, when the role of fluctuations is reduced, a mean-held approximation is justifiably employed to show the existence of tubelike structures reminiscent of Edwards' model.