Efficient broadband near-infrared phosphor Sr2ScSbO6:Cr3+ for solar-like lighting

被引:111
|
作者
Zhao, Meng [1 ]
Liu, Shengqiang [1 ]
Cai, Hao [1 ]
Zhao, Fangyi [1 ]
Song, Zhen [1 ]
Liu, Quanlin [1 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
broadband near-infrared; double-perovskite; Sr2ScSbO6:Cr3+; pc-LEDs; solar-like spectrum; SIMULATOR;
D O I
10.1007/s40843-021-1785-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
For healthy lighting, daily lighting that considers both visible light and near-infrared (NIR) light is necessary. However, at similar to 900 nm, the extensively used solar-like phosphor-converted light-emitting diodes (pc-LEDs) are limited by a lack of high-performance NIR luminescent materials. We report a broadband NIR phosphor Sr2ScSbO6:Cr3+ with a double perovskite-type structure, thus simultaneously demonstrating high luminescence efficiency and good thermal stability. Under 550-nm excitation, Sr2ScSbO6:Cr3+ demonstrates broadband NIR emission centered at similar to 890 nm with luminescence internal/external efficiencies of 82.0%/35.7%, respectively. Furthermore, the luminescence integrated intensity at 430 K remains at similar to 66.4% of the initial intensity. We successfully fabricated pc-LED devices using a 465-nm-sized blue chip and other commercial phosphors, presenting a relatively complete solar-like spectrum from blue to NIR light and is expected to be used in solar-like lighting.
引用
收藏
页码:748 / 756
页数:9
相关论文
共 50 条
  • [41] Distorted octahedral site occupation-induced high-efficiency broadband near-infrared emission in LiScGe2O6:Cr3+ phosphor
    Chen, X. H.
    Song, E. H.
    Zhou, Y. Y.
    He, F. Q.
    Yang, J. Q.
    Zhang, Q. Y.
    JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (39) : 13640 - 13646
  • [42] Efficient Near-Infrared Luminescence in Cr3+ Activated β-Alumina Structure Phosphor via Multiple-Sites Occupancy
    Li, Kai
    Wang, Dandan
    Wu, Dan
    Dong, Xiaoling
    Wang, Yue
    Liu, Yifan
    Zheng, Guojun
    Zhou, Wenping
    Zhang, Liangliang
    ADVANCED OPTICAL MATERIALS, 2025, 13 (06):
  • [43] Luminescent properties and LED Application of Broadband Near-Infrared Emitting NaInGe2O6: Cr3+ phosphors
    Zhou, Weiying
    Luo, Jiabao
    Fan, Jiaqi
    Pan, Haowen
    Zeng, Senxiang
    Zhou, Liya
    Pang, Qi
    Zhang, Xinguo
    CERAMICS INTERNATIONAL, 2021, 47 (18) : 25343 - 25349
  • [44] Efficient and Tunable Luminescence in Ga2-xInxO3:Cr3+ for Near-Infrared Imaging
    Zhong, Jiyou
    Zhuo, Ya
    Du, Fu
    Zhang, Hongshi
    Zhao, Weiren
    Brgoch, Jakoah
    ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (27) : 31835 - 31842
  • [45] Sr2MgWO6:Cr3+ phosphors with effective near-infrared fluorescence and long-lasting phosphorescence
    Xu, Dan-Dan
    Qiu, Zi-Cong
    Zhang, Qi
    Huang, Li-Juan
    Ye, Ying-Ying
    Cao, Li-Wei
    Meng, Jian-Xin
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 781 : 473 - 478
  • [46] Understanding the broadband near-infrared luminescence in a highly distorted garnet Ca4HfGe3O12:Cr3+ phosphor
    Liao, Zurong
    Zhong, Jiyou
    Li, Chaojie
    Jiang, Huan
    Zhao, Weiren
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (22) : 15452 - 15462
  • [47] Understanding the broadband near-infrared luminescence in a highly distorted garnet Ca4HfGe3O12:Cr3+ phosphor
    Liao, Zurong
    Zhong, Jiyou
    Li, Chaojie
    Jiang, Huan
    Zhao, Weiren
    Physical Chemistry Chemical Physics, 2023,
  • [48] Efficient and Broadband LiGaP2O7:Cr3+ Phosphors for Smart Near-Infrared Light-Emitting Diodes
    Yuan, Chenxu
    Li, Ruiyang
    Liu, Yongfu
    Zhang, Liangliang
    Zhang, Jiahua
    Leniec, Grzegorz
    Sun, Peng
    Liu, Zehua
    Luo, Zhaohua
    Dong, Rui
    Jiang, Jun
    LASER & PHOTONICS REVIEWS, 2021, 15 (11)
  • [49] Near-Infrared LuCa2ScZrGa2GeO12:Cr3+ Garnet Phosphor with Ultra-broadband Emission for NIR LED Applications
    Xie, Jihuan
    Tian, Junhang
    Zhuang, Weidong
    INORGANIC CHEMISTRY, 2023, 62 (27) : 10772 - 10779
  • [50] Luminescence properties of Cr3+-doped Al6Ge2O 13 broadband near-infrared phosphor
    Chi, Fengfeng
    Dai, Wenjuan
    Liu, Shengli
    Qiu, Liting
    Wei, Xiantao
    Chen, Yonghu
    Yin, Min
    OPTICAL MATERIALS, 2022, 126