Hydrolytic kinetic resolution of terminal epoxides catalyzed by novel bimetallic chiral Co (salen) complexes

被引：8
|
作者：
Kawthekar, Rahul B. [1 ]
Kim, Geon-Joong [1 ]
机构：
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
来源：
SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 08期
关键词：
asymmetric catalysis; chiral bimetallic complexes; hydrolytic kinetic resolution; terminal epoxides;
D O I：
10.1080/00397910701872658
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Novel bimetallic chiral Co (salen) complexes bearing transition-metal salts have been synthesized. The easily prepared complexes exhibited very high catalytic reactivity and enantioselectivity in hydrolytic kinetic resolution (HKR) of racemic terminal epoxides and consequently provided enantiomerically enriched epoxides (up to 99% ee).
引用
收藏
页码：1236 / 1248
页数：13
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