Molecular complexes of phenols with dicyclohexylamine

被引：1

作者：

Komissarova, NL ^{[1
]}

Vol'eva, VB ^{[1
]}

Belostotskaya, IS ^{[1
]}

Kurkovskaya, LN ^{[1
]}

Starikova, ZA ^{[1
]}

机构：

[1] Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 39卷 / 05期

关键词：

Chromatography; Phenol; Organic Chemistry; Molecular Complex; Bulky Substituent;

D O I：

10.1023/A:1026061313268

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Mannich reaction of 2,4-di-tert-butylphenol with dicyclohexylamine was found to involve formation of a stable 1:1 molecular complex between the phenol and amine. The complex does not change on melting sublimation, and chromatography on silica gel. Its structure was determined by X-ray analysis. Stable 1:1 complexes of dicyclohexylamine with a series of substituted phenols were synthesized; exceptions were 2,6-disubstituted phenols with bulky substituents.

引用

页码：686 / 688

页数：3

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