Molecular complexes of phenols with dicyclohexylamine

被引：1
|
作者：
Komissarova, NL [1 ]
Vol'eva, VB [1 ]
Belostotskaya, IS [1 ]
Kurkovskaya, LN [1 ]
Starikova, ZA [1 ]
机构：
[1] Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 39卷 / 05期
关键词：
Chromatography; Phenol; Organic Chemistry; Molecular Complex; Bulky Substituent;
D O I：
10.1023/A:1026061313268
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Mannich reaction of 2,4-di-tert-butylphenol with dicyclohexylamine was found to involve formation of a stable 1:1 molecular complex between the phenol and amine. The complex does not change on melting sublimation, and chromatography on silica gel. Its structure was determined by X-ray analysis. Stable 1:1 complexes of dicyclohexylamine with a series of substituted phenols were synthesized; exceptions were 2,6-disubstituted phenols with bulky substituents.
引用
收藏
页码：686 / 688
页数：3
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