Crystal structure and disorder of the fast oxide-ion conductor cubic Bi2O3

被引：144

作者：

Yashima, M ^{[1
]}

Ishimura, D ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Mat Sci & Engn, Interdisciplinary Grad Sch Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 378卷 / 3-4期

关键词：

D O I：

10.1016/j.cplett.2003.07.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Accurate nuclear density distribution of cubic bismuth oxide (delta-Bi2O3) has been obtained by the maximum entropy method (MEM)-based pattern fitting combined with the Rietveld method using neutron-powder-diffraction data. The result shows for the first time that the oxide ions have a complicated disorder spreading over a wide area and shift to the <111> directions from the ideal fluorite site. These features are responsible for the high oxide-ion conductivity. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：395 / 399

页数：5

共 50 条

[41] Effect of Gd and Ti co-doping on electrical performance of Bi2O3 oxygen ion conductor
Yang, Qiang
Luo, Zeyang
Zhu, Pei
Wei, Yunhe
Wang, Huan
Yan, Duanting
Wang, Dejun
Liu, Runru
MATERIALS RESEARCH EXPRESS, 2022, 9 (01)
[42] Doping effect on crystal structure of fast oxide ion conductor LaGaO3-based perovskite compounds
Kajitani, Masahiro
Matsuda, Motohide
Hoshikawa, Akinori
Kamiyama, Takashi
Izumi, Fujio
Miyake, Michihiro
ELECTROCERAMICS IN JAPAN IX, 2006, 320 : 227 - 230
[43] Structural disorder and ionic conduction: The case of Bi2O3
Depero, LE
Sangaletti, L
JOURNAL OF SOLID STATE CHEMISTRY, 1996, 122 (02) : 439 - 443
[44] Polymorphous nature of the local structure of δ-Bi2O3
Zhao, Xin-Gang
Malyi, Oleksandr I.
Zunger, Alex
PHYSICAL REVIEW MATERIALS, 2024, 8 (12):
[45] Structure and conductivity studies of electrodeposited δ-Bi2O3
Laurent, K.
Wang, G. Y.
Tusseau-Nenez, S.
Leprince-Wang, Y.
SOLID STATE IONICS, 2008, 178 (33-34) : 1735 - 1739
[46] ELECTRICAL PROPERTIES + DEFECT STRUCTURE OF BI2O3
HAPASE, MG
TARE, VB
BISWAS, AB
INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 1967, 5 (09) : 401 - &
[47] Structure and stability studies of electrodeposited δ-Bi2O3
Helfen, A
Merkourakis, S
Wang, G
Walls, MG
Roy, E
Yu-Zhang, K
Leprince-Wang, Y
SOLID STATE IONICS, 2005, 176 (5-6) : 629 - 633
[48] Electronic structure and chemical bonding in δ-Bi2O3
Inst of Solid State Chemistry, Ekaterinburg, Russia
J Phys Chem Solids, 9 (1243-1250):
[49] Evidence of metastability and demixion/recombination process in fast oxide-ion conductor La1.92Ca0.08Mo2O8.96
Selmi, Ania
Corbel, Gwenael
Lacorre, Philippe
SOLID STATE IONICS, 2006, 177 (35-36) : 3051 - 3055
[50] Synthesis, structure and properties of doped Bi2O3
Fruth, V.
Ianculescu, A.
Berger, D.
Preda, S.
Voicu, G.
Tenea, E.
Popa, M.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (14) : 3011 - 3016

← 1 2 3 4 5 →