Synthesis and X-ray diffraction study of K4[(UO2)2(C2O4)3(NCS)2] • 4H2O

被引：6
|
作者：
Serezhkina, L. B. [1 ]
Marukhnov, A. V. [1 ]
Peresypkina, E. V. [2 ]
Virovets, A. V. [2 ]
Medrish, I. V. [1 ]
Pushkin, D. V. [1 ]
机构：
[1] Samara State Univ, Samara 443011, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 06期
关键词：
Coordination Polyhedron; Potassium Atom; Uranium Atom; Oxalate Group; Main Structural Unit;
D O I：
10.1134/S0036023608060028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of K-4[(UO2)(2)(C2O4)(3)(NCS)(2)] center dot 4H(2)O(I) have been synthesized and studied by X-ray diffraction. The crystals are monoclinic with the unit cell parameters a = 8.0226(7) angstrom, b = 14.9493(11) angstrom, c = 11.1670(9) angstrom, beta = 98.299(3)degrees, space group P2(1)/n, Z = 2, V = 1325.26(19) angstrom(3), R = 0.0186. The main structural units of the crystals of structure I are discrete binuclear groups [(UO2)(2)(C2O4)(3)(NCS)(2)](4-) belonging to the crystal-chemical group A(2)K(02)B(2)(01) M-2(1) (A =UO22+, K-02 =C2O42-, B-01 =C2O42-, M-1 = NCS-) of the uranyl complexes. The uranium-containing complexes are linked into a three-dimensional framework through the potassium ions and a system of hydrogen bonds involving the outer-sphere water molecules.
引用
收藏
页码：837 / 841
页数：5
相关论文
共 50 条
  • [41] Crystal structure of Ba3[UO2(C2O4)2(NCS)]2 · 9H2O
    Zh. V. Akhmerkina
    E. V. Peresypkina
    A. V. Virovets
    L. B. Serezhkina
    Russian Journal of Inorganic Chemistry, 2008, 53 : 1396 - 1400
  • [42] Crystal structure of Ba3[UO2(C2O4)2(NCS)]2 • 9H2O
    Akhmerkina, Zh. V.
    Peresypkina, E. V.
    Virovets, A. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (09) : 1396 - 1400
  • [43] Crystal structure of K2[UO2(C2O4)(SO4)]•3H2O
    Artem'eva, MY
    Vologzhanina, AV
    Dolgushin, FM
    Antipin, MY
    Serezhkina, LB
    Serezhkin, VN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2004, 49 (12) : 1917 - 1922
  • [44] Synthesis and structure of (NH4)3[UO2(C3H2O4)2(NCS)] · 2H2O
    L. B. Serezhkina
    E. V. Peresypkina
    A. V. Virovets
    Ya. A. Medvedkov
    V. N. Serezhkin
    Crystallography Reports, 2014, 59 : 48 - 52
  • [45] Synthesis and structure of (NH4)3[UO2(C3H2O4)2(NCS)] • 2H2O
    Serezhkina, L. B.
    Peresypkina, E. V.
    Virovets, A. V.
    Medvedkov, Ya. A.
    Serezhkin, V. N.
    CRYSTALLOGRAPHY REPORTS, 2014, 59 (01) : 48 - 52
  • [46] Crystal structure of (CN3H6)3[UO2(C2O4)2(NCS)]
    Akhmerkina, ZV
    Dobrynin, AB
    Litvinov, IA
    Gorbunova, YE
    Mikhailov, YN
    Serezhkina, LB
    Serezhkin, VN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2004, 49 (09) : 1426 - 1431
  • [47] SYNTHESIS AND X-RAY STRUCTURE OF A NEW TC(IV) OXALATO COMPLEX - K4[(C2O4)2TC(MU-O)2TC(C2O4)2].3H2O
    ALBERTO, R
    ANDEREGG, G
    ALBINATI, A
    INORGANICA CHIMICA ACTA, 1990, 178 (01) : 125 - 130
  • [48] Synthesis and crystal structure of [(C5H5)3NH]4[(UO2)2(C2O4)(NCS)6]•H2O
    Akhmerkina, ZV
    Mikhailov, YN
    Gorbunova, YE
    Churakov, AV
    Serezhkina, LB
    Serezhkin, VN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (09) : 1326 - 1331
  • [49] Synthesis and X-ray diffraction study of cs3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)] and Cs5[UO2(CH3COO)3]3[UO2(NCS)4(H2O)] · 2H2O
    L. B. Serezhkina
    E. V. Peresypkina
    M. O. Karasev
    A. V. Virovets
    V. N. Serezhkin
    Russian Journal of Inorganic Chemistry, 2013, 58 : 160 - 165
  • [50] Synthesis and X-ray diffraction study of cs3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)] and Cs5[UO2(CH3COO)3]3[UO2(NCS)4(H2O)] • 2H2O
    Serezhkina, L. B.
    Peresypkina, E. V.
    Karasev, M. O.
    Virovets, A. V.
    Serezhkin, V. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (02) : 160 - 165
12345