Suppression of the polysulfide-shuttle behavior in Li-S batteries through the development of a facile functional group on the polypropylene separator

被引:68
|
作者
Yu, Xingwen
Joseph, Jorphin
Manthiram, Arumugam [1 ]
机构
[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
关键词
LITHIUM-SULFUR BATTERIES; CARBON COMPOSITES; PERFORMANCE; CATHODE; ELECTROCHEMISTRY; ELECTROLYTE; CHALLENGES; PROGRESS;
D O I
10.1039/c6mh00043f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Towards suppressing the polysulfide-shuttle behavior in lithium-sulfur (Li-S) batteries, a facile functional group has strategically been developed on the commercial polypropylene (PP) battery separator through a sequence of hydroxylating, grafting, and hydrolyzing processes. The Li-S cells with the modified PP separator shows significantly enhanced cyclability.
引用
收藏
页码:314 / 319
页数:6
相关论文
共 50 条
  • [21] Improving the polysulfide barrier by efficient carbon nanofibers coating on separator/cathode for Li-S batteries
    Garcia-Soriano, Francisco J.
    Para, M. Laura
    Luque, Guillermina L.
    Barraco, Daniel
    Leiva, Ezequiel P. M.
    Lener, German
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2020, 24 (10) : 2341 - 2351
  • [22] A nano rod-like α-MnO2 supported on carbon nanotubes modified separator inhibiting polysulfide shuttle in Li-S batteries
    Zu, Jiahao
    Jing, Weitao
    Dai, Xin
    Feng, Zheng
    Sun, Junjie
    Tan, Qiang
    Chen, Yuanzhen
    Liu, Yongning
    JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 933
  • [23] Hollow bimetallic sulfide composite coated separator for hindering the shuttle of polysulfides in Li-S batteries
    Jin, Lina
    Huang, Bingbing
    Qian, Xinye
    Chen, Jiangyu
    Cheng, Jian
    Hao, Qingyuan
    Zhang, Ke
    JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 926
  • [24] Taming the polysulphide shuttle in Li-S batteries by plasma-induced asymmetric functionalisation of the separator
    Conder, Joanna
    Urbonaite, Sigita
    Streich, Daniel
    Novak, Petr
    Gubler, Lorenz
    RSC ADVANCES, 2015, 5 (97): : 79654 - 79660
  • [25] Tin sulfide modified separator as an efficient polysulfide trapper for stable cycling performance in Li-S batteries
    Moorthy, Brindha
    Kwon, Soonho
    Kim, Joo-Hyung
    Ragupathy, P.
    Lee, Hyuck Mo
    Kim, Do Kyung
    NANOSCALE HORIZONS, 2019, 4 (01) : 214 - 222
  • [26] Aligned Bilayer of Single-Walled Carbon Nanotubes Suppresses the Polysulfide Shuttle in Li-S Batteries
    Ashraf, Muhammad Adeel
    Vegso, Karol
    Shaji, Ashin
    Bodik, Michal
    Sanchez, Mayela Garcia
    Zubair, Muhammad
    Din, Muhammad Faraz Ud
    Majkova, Eva
    Fedorkova, Andrea Strakova
    Keckes, Jozef
    Siffalovic, Peter
    ACS APPLIED ENERGY MATERIALS, 2022, 5 (12) : 15649 - 15655
  • [27] In Situ Built ZnS/MXene Heterostructure by a Mild Method for Inhibiting Polysulfide Shuttle in Li-S Batteries
    Liu, Ruyan
    Zhang, Jiudi
    Liu, Siyu
    Wang, Xinyang
    Qi, Min
    Dai, Binting
    Wang, Yali
    Ma, Lin
    Li, Junjie
    Yang, Jinzheng
    Jin, Zhanshuang
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (65)
  • [28] Rational Design of Nanostructured Functional Interlayer/Separator for Advanced Li-S Batteries
    Jeong, Yo Chan
    Kim, Jae Ho
    Nam, Seunghoon
    Park, Chong Rae
    Yang, Seung Jae
    ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (38)
  • [29] Polysulfide Filter and Dendrite Inhibitor: Highly Graphitized Wood Framework Inhibits Polysulfide Shuttle and Lithium Dendrites in Li-S Batteries
    Chen, Yuanzhen
    Zou, Kunyang
    Dai, Xin
    Bai, Haihua
    Zhang, Shilin
    Zhou, Tengfei
    Li, Chengxin
    Liu, Yongning
    Pang, Wei Kong
    Guo, Zaiping
    ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (31)
  • [30] Suppressed polysulfide shuttling and improved Li+ transport in Li-S batteries enabled by NbN modified PP separator
    Qiu, Weijian
    An, Cuihua
    Yan, Yawen
    Xu, Jun
    Zhang, Zhijia
    Guo, Wei
    Wang, Zhao
    Zheng, Zijian
    Wang, Zhengbang
    Deng, Qibo
    Li, Junsheng
    JOURNAL OF POWER SOURCES, 2019, 423 : 98 - 105