Domino-Ring Opening-Cyclization (DROC) of Donor-Acceptor (DA) Cyclopropanes

被引：37
|
作者：
Talukdar, Ranadeep [1 ]
Saha, Amrita [1 ]
Ghorai, Manas K. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2016年 / 56卷 / 6-7期
关键词：
carbocycles; donor-acceptor (DA) cyclopropane; domino-ring opening-cyclization (DROC); heterocycles; nucleophiles; AMINO-ACID-DERIVATIVES; BASE CATALYZED HYDROSILYLATION; ENANTIOSELECTIVE SYNTHESIS; BETA-ENAMINONITRILES; EFFICIENT SYNTHESIS; ACTIVATED AZIRIDINES; PHOSPHORORGANISCHE VERBINDUNGEN; SUBSTITUTED CYCLOPROPANES; HETEROCYCLIC SYNTHESIS; ASYMMETRIC-SYNTHESIS;
D O I：
10.1002/ijch.201500092
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new concept called domino-ring opening-cyclization (DROC) has been introduced by us where both the reactive centres of the DA cyclopropane participate in the bond formation, with a suitable reagent bearing both nucleophilic and electrophilic terminals in a domino fashion. The present review is intended to concisely describe the evolution of this new concept.
引用
收藏
页码：445 / 453
页数：9
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