Effect of Mn Precursors on Benzene Oxidation with Ozone Over MnOx/MCM-41 at Low Temperature

被引：11

作者：

Lee, Cho Rim ^{[1
]}

Jurng, Jongsoo ^{[2
]}

Bae, Gwi-Nam ^{[2
]}

Jeon, Jong-Ki ^{[3
]}

Kim, Sang Chai ^{[4
]}

Kim, Ji Man ^{[5
,6
]}

Jin, Mingshi ^{[5
,6
]}

Park, Young-Kwon ^{[1
,7
]}

机构：

[1] Univ Seoul, Grad Sch Energy & Environm Syst Engn, Seoul 130743, South Korea

[2] Korea Inst Sci & Technol, Environm Sensor Syst Res Ctr, Seoul 136791, South Korea

[3] Kongju Natl Univ, Dept Chem Engn, Cheonan 330717, South Korea

[4] Mokpo Natl Univ, Dept Environm Educ, Muan 534729, South Korea

[5] Sungkyunkwan Univ, Sch Mat Sci BK21, Dept Chem, Suwon 440476, South Korea

[6] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440476, South Korea

[7] Univ Seoul, Sch Environm Engn, Seoul 130743, South Korea

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2011年 / 11卷 / 08期

关键词：

Mn Precursors; MnOx/MCM-41; Catalytic Oxidation; Benzene; Ozone; SUPPORTED MANGANESE OXIDES; CATALYTIC-OXIDATION; PYROLYSIS;

D O I：

10.1166/jnn.2011.4789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low temperature benzene oxidation in the presence of ozone on MnOx/MCM-41 catalysts has been studied. MnOx/MCM-41 catalysts were prepared from two different precursors, Mn(NO3)(2) and Mn(CH3COO)(2), and these samples were characterized by N-2 sorption, X-ray diffraction, X-ray photoelectron spectroscopy and temperature programmed reduction. The characterization results showed that the MnOx/MCM-41 prepared from Mn(CH3COO)(2) had higher oxygen mobility and dispersion than the MnOx/MCM-41 from Mn(NO3)(2). As a result, the MnOx/MCM-41 obtained from Mn(CH3COO)(2) showed higher catalytic activity for the oxidation of benzene using ozone; however, without ozone, the catalytic activity was negligible.

引用

页码：7303 / 7306

页数：4

共 50 条

[31] Activity of Mo(II) allylic complexes supported in MCM-41 as oxidation catalysts precursors
Saraiva, Marta S.
Dias Filho, Newton L.
Nunes, Carla D.
Vaz, Pedro D.
Nunes, Teresa G.
Calhorda, Maria Jose
MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (03) : 670 - 677
[32] The properties of gold catalysts precursors adsorbed on the MCM-41 materials modified with Mn and Fe oxides
Wojciech Gac
Jacek Goworek
Grzegorz Wójcik
Leszek Kępinski
Adsorption, 2008, 14 : 247 - 256
[33] The properties of gold catalysts precursors adsorbed on the MCM-41 materials modified with Mn and Fe oxides
Gac, Wojciech
Goworek, Jacek
Wojcik, Grzegorz
Kepinski, Leszek
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2008, 14 (2-3): : 247 - 256
[34] Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41
A. Hamza
D. Srinivas
Catalysis Letters, 2009, 128 : 434 - 442
[35] Selective oxidation of CO in the presence of propylene over Ag/MCM-41 catalyst
Mamontov, G. V.
Gorbunova, A. S.
Vyshegorodtseva, E. V.
Zaikovskii, V. I.
Vodyankina, O. V.
CATALYSIS TODAY, 2019, 333 : 245 - 250
[36] Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41
Hamza, A.
Srinivas, D.
CATALYSIS LETTERS, 2009, 128 (3-4) : 434 - 442
[37] Liquid oxidation of cyclohexane to cyclohexanol over cerium-doped MCM-41
Yao, WH
Chen, YJ
Min, L
Fang, H
Yan, ZY
Wang, HL
Wang, JQ
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 246 (1-2) : 162 - 166
[38] Benzene Oxidation with Ozone Over MnOx/MSU-H and MnOx/Mesoporous-SAPO-34 Catalysts
An, Hyung Bum
Park, Sung Hoon
Jhurng, Sung Hwa
Jurng, Jong Soo
Bae, Gwi-Nam
Jeon, Jong-Ki
Park, Young-Kwon
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2015, 15 (01) : 454 - 458
[39] Ozone Catalytic Oxidation of HCHO in Air over MnOx at Room Temperature
Zhao Dezhi
Ding Tianying
Li Xiaosong
Liu Jinglin
Shi Chuan
Zhu Aimin
CHINESE JOURNAL OF CATALYSIS, 2012, 33 (03) : 396 - 401
[40] Vapour-phase oxidation of ethylbenzene with air over Mn-containing MCM-41 mesoporous molecular sieves
Vetrivel, S
Pandurangan, A
APPLIED CATALYSIS A-GENERAL, 2004, 264 (02) : 243 - 252

← 1 2 3 4 5 →