Synthesis of silver clusters in silica-based glasses for optoelectronics applications

被引：97
|
作者：
Borsella, E
Cattaruzza, E
De Marchi, G
Gonella, F
Mattei, G
Mazzoldi, P
Quaranta, A
Battaglin, G
Polloni, R
机构：
[1] INFM, Dipartimento Fis, I-35131 Padua, Italy
[2] INFM, I-38050 Trento, Italy
[3] Dipartimento Ingn Mat, I-38050 Trento, Italy
[4] INFM, Dipartimento Chim Fis, I-30123 Venice, Italy
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 1999年 / 245卷
关键词：
D O I：
10.1016/S0022-3093(98)00878-3
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The techniques of silver-sodium ion exchange and Ag+ ion implantation in glass have been successfully applied for producing silver clusters in soda-lime glass optical waveguides. Optical absorption spectroscopy, time and spectrally resolved photoluminescence, Rutherford backscattering spectrometry, X-ray photoelectron spectroscopy and transmission electron microscopy measurements were made. Structural changes of the Ag+ environment were observed in ion-exchanged samples prepared in liquids with different Ag+ concentrations. Heat treatments in air and in H-2 atmospheres induced cluster formation in ion-exchanged samples through different reduction-migration mechanisms, whereas clusters formation in ion-implanted samples is related to the defect concentrations induced by the radiation damage. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：122 / 128
页数：7
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